Cystamindi-ium tetrachlorocuprate [NH3(CH2)2SS(CH2)2NH3][CuCl4]: synthesis, crystal structure, and thermal decomposition
The salt [NH3(CH2)2SS(CH2)2NH3][CuCl4] was obtained by crystallization after adding CuCl2 to cystamine (Cysta), solved in hydrochloric acid. The assumption of conserved disulfide connection (S–S) in the compound, made on the basis of infrared spectroscopy, is further supported by the crystal structu...
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| Veröffentlicht in: | Powder diffraction 2015-06, Vol.30 (2), p.163-169 |
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| creator | Leshok, D. Y. Golovnev, N. N. Kirik, S. D. |
| description | The salt [NH3(CH2)2SS(CH2)2NH3][CuCl4] was obtained by crystallization after adding CuCl2 to cystamine (Cysta), solved in hydrochloric acid. The assumption of conserved disulfide connection (S–S) in the compound, made on the basis of infrared spectroscopy, is further supported by the crystal structure determined from X-ray powder diffraction data. The compound has an ionic structure. [CuCl4]2− and CystaH2
2+ ions package in the form of inorganic and organic layers in the cell, interconnected through the formation of hydrogen bonds via NH3-groups and chlorine atoms of the complex [CuCl4]2−. Inorganic layers are additionally stabilized in the parquet package of [CuCl4]2− ions which provides a Cu-distorted octahedral coordination. CystaH2[CuCl4] is stable in air up to 200 °C. Thermal decomposition occurs in several stages, accompanied by breaking of S–S bonds, releasing of the organic component and yielding CuO. |
| doi_str_mv | 10.1017/S0885715614001390 |
| format | Article |
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2+ ions package in the form of inorganic and organic layers in the cell, interconnected through the formation of hydrogen bonds via NH3-groups and chlorine atoms of the complex [CuCl4]2−. Inorganic layers are additionally stabilized in the parquet package of [CuCl4]2− ions which provides a Cu-distorted octahedral coordination. CystaH2[CuCl4] is stable in air up to 200 °C. Thermal decomposition occurs in several stages, accompanied by breaking of S–S bonds, releasing of the organic component and yielding CuO.</description><identifier>ISSN: 0885-7156</identifier><identifier>EISSN: 1945-7413</identifier><identifier>DOI: 10.1017/S0885715614001390</identifier><language>eng</language><publisher>New York, USA: Cambridge University Press</publisher><subject>Breaking ; Chemical bonds ; CONNECTORS (ELECTRICAL) ; COPPER OXIDE ; CRYSTAL STRUCTURE ; Crystallization ; DECOMPOSITION ; Diffraction ; Infrared spectroscopy ; Packages ; Technical Articles ; Thermal decomposition</subject><ispartof>Powder diffraction, 2015-06, Vol.30 (2), p.163-169</ispartof><rights>Copyright © International Centre for Diffraction Data 2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c420t-5119983d01107fa2a4f69259450580e32def3fd0c838a9f8ef607169ca75331e3</citedby><cites>FETCH-LOGICAL-c420t-5119983d01107fa2a4f69259450580e32def3fd0c838a9f8ef607169ca75331e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.cambridge.org/core/product/identifier/S0885715614001390/type/journal_article$$EHTML$$P50$$Gcambridge$$H</linktohtml><link.rule.ids>164,314,780,784,27924,27925,55628</link.rule.ids></links><search><creatorcontrib>Leshok, D. Y.</creatorcontrib><creatorcontrib>Golovnev, N. N.</creatorcontrib><creatorcontrib>Kirik, S. D.</creatorcontrib><title>Cystamindi-ium tetrachlorocuprate [NH3(CH2)2SS(CH2)2NH3][CuCl4]: synthesis, crystal structure, and thermal decomposition</title><title>Powder diffraction</title><addtitle>Powder Diffr</addtitle><description>The salt [NH3(CH2)2SS(CH2)2NH3][CuCl4] was obtained by crystallization after adding CuCl2 to cystamine (Cysta), solved in hydrochloric acid. The assumption of conserved disulfide connection (S–S) in the compound, made on the basis of infrared spectroscopy, is further supported by the crystal structure determined from X-ray powder diffraction data. The compound has an ionic structure. [CuCl4]2− and CystaH2
2+ ions package in the form of inorganic and organic layers in the cell, interconnected through the formation of hydrogen bonds via NH3-groups and chlorine atoms of the complex [CuCl4]2−. Inorganic layers are additionally stabilized in the parquet package of [CuCl4]2− ions which provides a Cu-distorted octahedral coordination. CystaH2[CuCl4] is stable in air up to 200 °C. Thermal decomposition occurs in several stages, accompanied by breaking of S–S bonds, releasing of the organic component and yielding CuO.</description><subject>Breaking</subject><subject>Chemical bonds</subject><subject>CONNECTORS (ELECTRICAL)</subject><subject>COPPER OXIDE</subject><subject>CRYSTAL STRUCTURE</subject><subject>Crystallization</subject><subject>DECOMPOSITION</subject><subject>Diffraction</subject><subject>Infrared spectroscopy</subject><subject>Packages</subject><subject>Technical Articles</subject><subject>Thermal decomposition</subject><issn>0885-7156</issn><issn>1945-7413</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kVFLwzAUhYMoOKc_wLeCLxOs5jZNk_gmRZ0g-jB9GqPENHUZbTOTFNy_N2M-iOLThXO-c7iXi9Ap4EvAwK5mmHPKgBaQYwxE4D00ApHTlOVA9tFoa6db_xAdeb-KDHCajdBnufFBdqavTWqGLgk6OKmWrXVWDWsng07mT1MyKafZeTab7WYUFvNyKNt8cZ34TR-W2ht_kSi3LWsTH9ygwuD0RSL7Oom266Jca2W7tfUmGNsfo4NGtl6ffM8xer27fSmn6ePz_UN585iqPMMhpQBCcFLHfTFrZCbzphAZjZdhyrEmWa0b0tRYccKlaLhuCsygEEoySghoMkaTXe_a2Y9B-1B1xivdtrLXdvAVMCxYzjPKI3r2C13ZwfVxuwoKLnjOOBaRgh2lnPXe6aZaO9NJt6kAV9tfVH9-ETPkOyO7N2fqd_2j-t_UFyJyiV8</recordid><startdate>20150601</startdate><enddate>20150601</enddate><creator>Leshok, D. 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D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c420t-5119983d01107fa2a4f69259450580e32def3fd0c838a9f8ef607169ca75331e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Breaking</topic><topic>Chemical bonds</topic><topic>CONNECTORS (ELECTRICAL)</topic><topic>COPPER OXIDE</topic><topic>CRYSTAL STRUCTURE</topic><topic>Crystallization</topic><topic>DECOMPOSITION</topic><topic>Diffraction</topic><topic>Infrared spectroscopy</topic><topic>Packages</topic><topic>Technical Articles</topic><topic>Thermal decomposition</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Leshok, D. Y.</creatorcontrib><creatorcontrib>Golovnev, N. N.</creatorcontrib><creatorcontrib>Kirik, S. D.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>DELNET Engineering & Technology Collection</collection><collection>Copper Technical Reference Library</collection><jtitle>Powder diffraction</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Leshok, D. Y.</au><au>Golovnev, N. N.</au><au>Kirik, S. D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cystamindi-ium tetrachlorocuprate [NH3(CH2)2SS(CH2)2NH3][CuCl4]: synthesis, crystal structure, and thermal decomposition</atitle><jtitle>Powder diffraction</jtitle><addtitle>Powder Diffr</addtitle><date>2015-06-01</date><risdate>2015</risdate><volume>30</volume><issue>2</issue><spage>163</spage><epage>169</epage><pages>163-169</pages><issn>0885-7156</issn><eissn>1945-7413</eissn><abstract>The salt [NH3(CH2)2SS(CH2)2NH3][CuCl4] was obtained by crystallization after adding CuCl2 to cystamine (Cysta), solved in hydrochloric acid. The assumption of conserved disulfide connection (S–S) in the compound, made on the basis of infrared spectroscopy, is further supported by the crystal structure determined from X-ray powder diffraction data. The compound has an ionic structure. [CuCl4]2− and CystaH2
2+ ions package in the form of inorganic and organic layers in the cell, interconnected through the formation of hydrogen bonds via NH3-groups and chlorine atoms of the complex [CuCl4]2−. Inorganic layers are additionally stabilized in the parquet package of [CuCl4]2− ions which provides a Cu-distorted octahedral coordination. CystaH2[CuCl4] is stable in air up to 200 °C. Thermal decomposition occurs in several stages, accompanied by breaking of S–S bonds, releasing of the organic component and yielding CuO.</abstract><cop>New York, USA</cop><pub>Cambridge University Press</pub><doi>10.1017/S0885715614001390</doi><tpages>7</tpages></addata></record> |
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| source | Cambridge University Press Journals Complete |
| subjects | Breaking Chemical bonds CONNECTORS (ELECTRICAL) COPPER OXIDE CRYSTAL STRUCTURE Crystallization DECOMPOSITION Diffraction Infrared spectroscopy Packages Technical Articles Thermal decomposition |
| title | Cystamindi-ium tetrachlorocuprate [NH3(CH2)2SS(CH2)2NH3][CuCl4]: synthesis, crystal structure, and thermal decomposition |
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