Enantio- and diastereoselective asymmetric allylic alkylation catalyzed by a planar-chiral cyclopentadienyl ruthenium complex

We report asymmetric allylic alkylation of allylic chloride with β-diketones as the prochiral carbon nucleophiles using a planar-chiral Cp'Ru catalyst. The reaction proceeds under mild conditions; the resulting chiral products containing vicinal tertiary stereocenters are obtained with high reg...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2015-07, Vol.51 (54), p.10895-10898
Hauptverfasser:	Kanbayashi, Naoya, Hosoda, Kazuki, Kato, Masanori, Takii, Koichiro, Okamura, Taka-aki, Onitsuka, Kiyotaka
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkylation Asymmetry Carbon Catalysts Chlorides Diols Nucleophiles Ruthenium
Online-Zugang:	Volltext
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