Hydrogen Bonded Multilayer Films Based on Poly(2-oxazoline)s and Tannic Acid
In recent years, the layer‐by‐layer (LbL) assembly based on hydrogen bonding interactions is gaining popularity for the preparation of thin film coatings, especially for biomedical purposes, based on the use of neutral, non‐toxic building blocks. The use of tannic acid (TA) as hydrogen bonding donor...
Gespeichert in:
| Veröffentlicht in: | Advanced healthcare materials 2014-12, Vol.3 (12), p.2040-2047 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 2047 |
|---|---|
| container_issue | 12 |
| container_start_page | 2040 |
| container_title | Advanced healthcare materials |
| container_volume | 3 |
| creator | Sundaramurthy, Anandhakumar Vergaelen, Maarten Maji, Samarendra Auzély-Velty, Rachel Zhang, Zhiyue De Geest, Bruno G. Hoogenboom, Richard |
| description | In recent years, the layer‐by‐layer (LbL) assembly based on hydrogen bonding interactions is gaining popularity for the preparation of thin film coatings, especially for biomedical purposes, based on the use of neutral, non‐toxic building blocks. The use of tannic acid (TA) as hydrogen bonding donor is especially interesting as it results in LbL films that are stable under physiological conditions. In this work, investigations on the LbL thin film preparation of TA with poly(2‐oxazoline)s with varying hydrophilicity, namely poly(2‐methyl‐2‐oxazoline) (PMeOx), poly(2‐ethyl‐2‐oxazoline) (PEtOx) and poly(2‐n‐propyl‐2‐oxazoline) (PnPropOx), are reported. The LbL assembly process is investigated by quartz crystal microbalance and UV‐vis spectroscopy revealing linear growth of the film thickness. Furthermore, isothermal titration calorimetry demonstrates the LbL assembly of TA, and PMeOx is found to be mostly enthalpy driven while the LbL assembly of TA with PEtOx and PnPropOx is mostly entropy driven. Finally, scanning electron microscopy and ellipsometry demonstrate the formation of smooth thin films for LbL assembly of TA with all three polymers. Such poly(2‐oxazoline) coatings have high potential for use as anti‐biofouling coatings.
The layer‐by‐layer assembly of tannic acid and poly(2‐oxazoline)s is reported for the preparation of smooth thin films. The variation of the poly(2‐oxazoline) side chain allows a detailed evaluation of the effect of polymer hydrophilicity on the thermodynamic driven forces for the LbL assembly process. |
| doi_str_mv | 10.1002/adhm.201400377 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1709725647</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1701482164</sourcerecordid><originalsourceid>FETCH-LOGICAL-c5077-f340a6cafa97d346f97fca29246b08e7d2e1e0d6b4b34b3a4a915ebfab6d4803</originalsourceid><addsrcrecordid>eNqNkd1rFDEUxQdRbKl99VEGRKgPsyaZfEwet9XtFrZ-Lgp9CXcmGU3NJDXZwY5_fWfYdRVfaggkXH7n5N6cLHuK0QwjRF6B_tbNCMIUoVKIB9khwZIUhDP5cH-n6CA7TukajYszzCv8ODsgjAiKOT3MVstBx_DV-Pw0eG10ftm7jXUwmJgvrOtSfgppLAefvw9uOCFFuIVfwVlvXqYcvM7X4L1t8nlj9ZPsUQsumePdeZStF2_WZ8ti9e784my-KhqGhCjakiLgDbQghS4pb6VoGyCSUF6jyghNDDZI85rW5biBgsTM1C3UXNMKlUfZydb2JoYfvUkb1dnUGOfAm9AnhQWSgjBOxf-gmFZk_Ir7UV4yhEQlpgae_4Nehz76ceSJorSqGJmo2ZZqYkgpmlbdRNtBHBRGaspPTfmpfX6j4NnOtq87o_f477RG4MUOgNSAayP4xqY_nESE82oyklvup3VmuOdZNX-9vPy7iWKrtWljbvdaiN8VF6Vg6svbc3X1ec0-fbz6oBblHdgCv-Y</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1634488520</pqid></control><display><type>article</type><title>Hydrogen Bonded Multilayer Films Based on Poly(2-oxazoline)s and Tannic Acid</title><source>MEDLINE</source><source>Wiley Online Library Journals Frontfile Complete</source><creator>Sundaramurthy, Anandhakumar ; Vergaelen, Maarten ; Maji, Samarendra ; Auzély-Velty, Rachel ; Zhang, Zhiyue ; De Geest, Bruno G. ; Hoogenboom, Richard</creator><creatorcontrib>Sundaramurthy, Anandhakumar ; Vergaelen, Maarten ; Maji, Samarendra ; Auzély-Velty, Rachel ; Zhang, Zhiyue ; De Geest, Bruno G. ; Hoogenboom, Richard</creatorcontrib><description>In recent years, the layer‐by‐layer (LbL) assembly based on hydrogen bonding interactions is gaining popularity for the preparation of thin film coatings, especially for biomedical purposes, based on the use of neutral, non‐toxic building blocks. The use of tannic acid (TA) as hydrogen bonding donor is especially interesting as it results in LbL films that are stable under physiological conditions. In this work, investigations on the LbL thin film preparation of TA with poly(2‐oxazoline)s with varying hydrophilicity, namely poly(2‐methyl‐2‐oxazoline) (PMeOx), poly(2‐ethyl‐2‐oxazoline) (PEtOx) and poly(2‐n‐propyl‐2‐oxazoline) (PnPropOx), are reported. The LbL assembly process is investigated by quartz crystal microbalance and UV‐vis spectroscopy revealing linear growth of the film thickness. Furthermore, isothermal titration calorimetry demonstrates the LbL assembly of TA, and PMeOx is found to be mostly enthalpy driven while the LbL assembly of TA with PEtOx and PnPropOx is mostly entropy driven. Finally, scanning electron microscopy and ellipsometry demonstrate the formation of smooth thin films for LbL assembly of TA with all three polymers. Such poly(2‐oxazoline) coatings have high potential for use as anti‐biofouling coatings.
The layer‐by‐layer assembly of tannic acid and poly(2‐oxazoline)s is reported for the preparation of smooth thin films. The variation of the poly(2‐oxazoline) side chain allows a detailed evaluation of the effect of polymer hydrophilicity on the thermodynamic driven forces for the LbL assembly process.</description><identifier>ISSN: 2192-2640</identifier><identifier>EISSN: 2192-2659</identifier><identifier>DOI: 10.1002/adhm.201400377</identifier><identifier>PMID: 25274164</identifier><language>eng</language><publisher>Weinheim: Blackwell Publishing Ltd</publisher><subject>Applied sciences ; Assembly ; Biocompatible Materials - chemistry ; Biological and medical sciences ; Chemical bonds ; Coatings ; Exact sciences and technology ; Hydrogen Bonding ; Hydrophilicity ; LbL assembly ; Materials Testing ; Medical sciences ; Microbalances ; Oxazoles - chemistry ; Physicochemistry of polymers ; poly(2-oxazoline)s ; Polymers ; Surgery (general aspects). Transplantations, organ and tissue grafts. Graft diseases ; Tannic acid ; Tannins - chemistry ; Technology. Biomaterials. Equipments ; thermodynamics ; Thin film coatings ; Thin films</subject><ispartof>Advanced healthcare materials, 2014-12, Vol.3 (12), p.2040-2047</ispartof><rights>2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2015 INIST-CNRS</rights><rights>2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5077-f340a6cafa97d346f97fca29246b08e7d2e1e0d6b4b34b3a4a915ebfab6d4803</citedby><cites>FETCH-LOGICAL-c5077-f340a6cafa97d346f97fca29246b08e7d2e1e0d6b4b34b3a4a915ebfab6d4803</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fadhm.201400377$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fadhm.201400377$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=29026687$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25274164$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Sundaramurthy, Anandhakumar</creatorcontrib><creatorcontrib>Vergaelen, Maarten</creatorcontrib><creatorcontrib>Maji, Samarendra</creatorcontrib><creatorcontrib>Auzély-Velty, Rachel</creatorcontrib><creatorcontrib>Zhang, Zhiyue</creatorcontrib><creatorcontrib>De Geest, Bruno G.</creatorcontrib><creatorcontrib>Hoogenboom, Richard</creatorcontrib><title>Hydrogen Bonded Multilayer Films Based on Poly(2-oxazoline)s and Tannic Acid</title><title>Advanced healthcare materials</title><addtitle>Adv. Healthcare Mater</addtitle><description>In recent years, the layer‐by‐layer (LbL) assembly based on hydrogen bonding interactions is gaining popularity for the preparation of thin film coatings, especially for biomedical purposes, based on the use of neutral, non‐toxic building blocks. The use of tannic acid (TA) as hydrogen bonding donor is especially interesting as it results in LbL films that are stable under physiological conditions. In this work, investigations on the LbL thin film preparation of TA with poly(2‐oxazoline)s with varying hydrophilicity, namely poly(2‐methyl‐2‐oxazoline) (PMeOx), poly(2‐ethyl‐2‐oxazoline) (PEtOx) and poly(2‐n‐propyl‐2‐oxazoline) (PnPropOx), are reported. The LbL assembly process is investigated by quartz crystal microbalance and UV‐vis spectroscopy revealing linear growth of the film thickness. Furthermore, isothermal titration calorimetry demonstrates the LbL assembly of TA, and PMeOx is found to be mostly enthalpy driven while the LbL assembly of TA with PEtOx and PnPropOx is mostly entropy driven. Finally, scanning electron microscopy and ellipsometry demonstrate the formation of smooth thin films for LbL assembly of TA with all three polymers. Such poly(2‐oxazoline) coatings have high potential for use as anti‐biofouling coatings.
The layer‐by‐layer assembly of tannic acid and poly(2‐oxazoline)s is reported for the preparation of smooth thin films. The variation of the poly(2‐oxazoline) side chain allows a detailed evaluation of the effect of polymer hydrophilicity on the thermodynamic driven forces for the LbL assembly process.</description><subject>Applied sciences</subject><subject>Assembly</subject><subject>Biocompatible Materials - chemistry</subject><subject>Biological and medical sciences</subject><subject>Chemical bonds</subject><subject>Coatings</subject><subject>Exact sciences and technology</subject><subject>Hydrogen Bonding</subject><subject>Hydrophilicity</subject><subject>LbL assembly</subject><subject>Materials Testing</subject><subject>Medical sciences</subject><subject>Microbalances</subject><subject>Oxazoles - chemistry</subject><subject>Physicochemistry of polymers</subject><subject>poly(2-oxazoline)s</subject><subject>Polymers</subject><subject>Surgery (general aspects). Transplantations, organ and tissue grafts. Graft diseases</subject><subject>Tannic acid</subject><subject>Tannins - chemistry</subject><subject>Technology. Biomaterials. Equipments</subject><subject>thermodynamics</subject><subject>Thin film coatings</subject><subject>Thin films</subject><issn>2192-2640</issn><issn>2192-2659</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqNkd1rFDEUxQdRbKl99VEGRKgPsyaZfEwet9XtFrZ-Lgp9CXcmGU3NJDXZwY5_fWfYdRVfaggkXH7n5N6cLHuK0QwjRF6B_tbNCMIUoVKIB9khwZIUhDP5cH-n6CA7TukajYszzCv8ODsgjAiKOT3MVstBx_DV-Pw0eG10ftm7jXUwmJgvrOtSfgppLAefvw9uOCFFuIVfwVlvXqYcvM7X4L1t8nlj9ZPsUQsumePdeZStF2_WZ8ti9e784my-KhqGhCjakiLgDbQghS4pb6VoGyCSUF6jyghNDDZI85rW5biBgsTM1C3UXNMKlUfZydb2JoYfvUkb1dnUGOfAm9AnhQWSgjBOxf-gmFZk_Ir7UV4yhEQlpgae_4Nehz76ceSJorSqGJmo2ZZqYkgpmlbdRNtBHBRGaspPTfmpfX6j4NnOtq87o_f477RG4MUOgNSAayP4xqY_nESE82oyklvup3VmuOdZNX-9vPy7iWKrtWljbvdaiN8VF6Vg6svbc3X1ec0-fbz6oBblHdgCv-Y</recordid><startdate>201412</startdate><enddate>201412</enddate><creator>Sundaramurthy, Anandhakumar</creator><creator>Vergaelen, Maarten</creator><creator>Maji, Samarendra</creator><creator>Auzély-Velty, Rachel</creator><creator>Zhang, Zhiyue</creator><creator>De Geest, Bruno G.</creator><creator>Hoogenboom, Richard</creator><general>Blackwell Publishing Ltd</general><general>Wiley-VCH</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QP</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7T5</scope><scope>7TA</scope><scope>7TB</scope><scope>7TM</scope><scope>7TO</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>H94</scope><scope>JG9</scope><scope>JQ2</scope><scope>K9.</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>7X8</scope><scope>7QO</scope><scope>P64</scope></search><sort><creationdate>201412</creationdate><title>Hydrogen Bonded Multilayer Films Based on Poly(2-oxazoline)s and Tannic Acid</title><author>Sundaramurthy, Anandhakumar ; Vergaelen, Maarten ; Maji, Samarendra ; Auzély-Velty, Rachel ; Zhang, Zhiyue ; De Geest, Bruno G. ; Hoogenboom, Richard</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5077-f340a6cafa97d346f97fca29246b08e7d2e1e0d6b4b34b3a4a915ebfab6d4803</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Applied sciences</topic><topic>Assembly</topic><topic>Biocompatible Materials - chemistry</topic><topic>Biological and medical sciences</topic><topic>Chemical bonds</topic><topic>Coatings</topic><topic>Exact sciences and technology</topic><topic>Hydrogen Bonding</topic><topic>Hydrophilicity</topic><topic>LbL assembly</topic><topic>Materials Testing</topic><topic>Medical sciences</topic><topic>Microbalances</topic><topic>Oxazoles - chemistry</topic><topic>Physicochemistry of polymers</topic><topic>poly(2-oxazoline)s</topic><topic>Polymers</topic><topic>Surgery (general aspects). Transplantations, organ and tissue grafts. Graft diseases</topic><topic>Tannic acid</topic><topic>Tannins - chemistry</topic><topic>Technology. Biomaterials. Equipments</topic><topic>thermodynamics</topic><topic>Thin film coatings</topic><topic>Thin films</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sundaramurthy, Anandhakumar</creatorcontrib><creatorcontrib>Vergaelen, Maarten</creatorcontrib><creatorcontrib>Maji, Samarendra</creatorcontrib><creatorcontrib>Auzély-Velty, Rachel</creatorcontrib><creatorcontrib>Zhang, Zhiyue</creatorcontrib><creatorcontrib>De Geest, Bruno G.</creatorcontrib><creatorcontrib>Hoogenboom, Richard</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Calcium & Calcified Tissue Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Immunology Abstracts</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Nucleic Acids Abstracts</collection><collection>Oncogenes and Growth Factors Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>AIDS and Cancer Research Abstracts</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>MEDLINE - Academic</collection><collection>Biotechnology Research Abstracts</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Advanced healthcare materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sundaramurthy, Anandhakumar</au><au>Vergaelen, Maarten</au><au>Maji, Samarendra</au><au>Auzély-Velty, Rachel</au><au>Zhang, Zhiyue</au><au>De Geest, Bruno G.</au><au>Hoogenboom, Richard</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrogen Bonded Multilayer Films Based on Poly(2-oxazoline)s and Tannic Acid</atitle><jtitle>Advanced healthcare materials</jtitle><addtitle>Adv. Healthcare Mater</addtitle><date>2014-12</date><risdate>2014</risdate><volume>3</volume><issue>12</issue><spage>2040</spage><epage>2047</epage><pages>2040-2047</pages><issn>2192-2640</issn><eissn>2192-2659</eissn><abstract>In recent years, the layer‐by‐layer (LbL) assembly based on hydrogen bonding interactions is gaining popularity for the preparation of thin film coatings, especially for biomedical purposes, based on the use of neutral, non‐toxic building blocks. The use of tannic acid (TA) as hydrogen bonding donor is especially interesting as it results in LbL films that are stable under physiological conditions. In this work, investigations on the LbL thin film preparation of TA with poly(2‐oxazoline)s with varying hydrophilicity, namely poly(2‐methyl‐2‐oxazoline) (PMeOx), poly(2‐ethyl‐2‐oxazoline) (PEtOx) and poly(2‐n‐propyl‐2‐oxazoline) (PnPropOx), are reported. The LbL assembly process is investigated by quartz crystal microbalance and UV‐vis spectroscopy revealing linear growth of the film thickness. Furthermore, isothermal titration calorimetry demonstrates the LbL assembly of TA, and PMeOx is found to be mostly enthalpy driven while the LbL assembly of TA with PEtOx and PnPropOx is mostly entropy driven. Finally, scanning electron microscopy and ellipsometry demonstrate the formation of smooth thin films for LbL assembly of TA with all three polymers. Such poly(2‐oxazoline) coatings have high potential for use as anti‐biofouling coatings.
The layer‐by‐layer assembly of tannic acid and poly(2‐oxazoline)s is reported for the preparation of smooth thin films. The variation of the poly(2‐oxazoline) side chain allows a detailed evaluation of the effect of polymer hydrophilicity on the thermodynamic driven forces for the LbL assembly process.</abstract><cop>Weinheim</cop><pub>Blackwell Publishing Ltd</pub><pmid>25274164</pmid><doi>10.1002/adhm.201400377</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2192-2640 |
| ispartof | Advanced healthcare materials, 2014-12, Vol.3 (12), p.2040-2047 |
| issn | 2192-2640 2192-2659 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1709725647 |
| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences Assembly Biocompatible Materials - chemistry Biological and medical sciences Chemical bonds Coatings Exact sciences and technology Hydrogen Bonding Hydrophilicity LbL assembly Materials Testing Medical sciences Microbalances Oxazoles - chemistry Physicochemistry of polymers poly(2-oxazoline)s Polymers Surgery (general aspects). Transplantations, organ and tissue grafts. Graft diseases Tannic acid Tannins - chemistry Technology. Biomaterials. Equipments thermodynamics Thin film coatings Thin films |
| title | Hydrogen Bonded Multilayer Films Based on Poly(2-oxazoline)s and Tannic Acid |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-08T00%3A58%3A15IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Hydrogen%20Bonded%20Multilayer%20Films%20Based%20on%20Poly(2-oxazoline)s%20and%20Tannic%20Acid&rft.jtitle=Advanced%20healthcare%20materials&rft.au=Sundaramurthy,%20Anandhakumar&rft.date=2014-12&rft.volume=3&rft.issue=12&rft.spage=2040&rft.epage=2047&rft.pages=2040-2047&rft.issn=2192-2640&rft.eissn=2192-2659&rft_id=info:doi/10.1002/adhm.201400377&rft_dat=%3Cproquest_cross%3E1701482164%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1634488520&rft_id=info:pmid/25274164&rfr_iscdi=true |