Brønsted Acid-Catalyzed Cascade Reactions Involving 1,2-Indole Migration

A cascade reaction of indoles with propargylic diols involving an unprecedented metal‐free 1,2‐indole migration onto an alkyne was carried out. DFT calculations support a mechanism consisting of a concerted nucleophilic attack of the indole nucleus with loss of water, followed by the 1,2‐migration a...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Chemistry : a European journal 2015-09, Vol.21 (37), p.12889-12893
Hauptverfasser:	Álvarez, Estela, Nieto Faza, Olalla, Silva López, Carlos, Fernández-Rodríguez, Manuel A., Sanz, Roberto
Format:	Artikel
Sprache:	eng
Schlagworte:	benzofulvenes Brønsted acid catalysis Chemistry indole migration Nazarov cyclization
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!