Copper(I)-Catalyzed Kinetic Resolution of N‑Sulfonylaziridines with Indoles: Efficient Construction of Pyrroloindolines

The first Lewis acid catalyzed [3 + 2] annulation of indoles and 2-aryl-N-tosylaziridines was realized by using copper­(I)/chiral diphosphine complexes as a catalyst. With this method, a variety of uniquely substituted chiral pyrroloindolines bearing multiple contiguous stereogenic centers were faci...

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Veröffentlicht in:	Journal of the American Chemical Society 2015-08, Vol.137 (32), p.10088-10091
Hauptverfasser:	Chai, Zhuo, Zhu, You-Min, Yang, Pei-Jun, Wang, Shaoyin, Wang, Shaowu, Liu, Zhen, Yang, Gaosheng
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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