Unsaturated polyester resins for thermoset applications using renewable isosorbide as a component for property improvement
ABSTRACT Unsaturated polyester (UPE) resins are used in a variety of thermosetting applications due to the reduced cost when compared to epoxy resins; however, UPE resins also have reduced thermomechanical performance. Investigating avenues to improve the performance of UPEs has led to the use of bi...
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| Veröffentlicht in: | Journal of applied polymer science 2015-08, Vol.132 (30), p.np-n/a |
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| container_title | Journal of applied polymer science |
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| creator | Sadler, Joshua M. Toulan, Faye R. Palmese, Giuseppe R. La Scala, John J. |
| description | ABSTRACT
Unsaturated polyester (UPE) resins are used in a variety of thermosetting applications due to the reduced cost when compared to epoxy resins; however, UPE resins also have reduced thermomechanical performance. Investigating avenues to improve the performance of UPEs has led to the use of bio‐based starting materials as structural components of the synthesized prepolymers as a result of their advantageous structural features. Isosorbide, a compound derived from renewable feedstocks, has been utilized to provide additional stiffness from the diol component for novel unsaturated polyesters resins. These resins have been shown to possess Tg's (32−72°C) and storage moduli (540−2200 MPa) that are in the desired range for composite materials with viscosities (1.2−25 Pa s) amenable to a variety of liquid molding techniques. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42315. |
| doi_str_mv | 10.1002/app.42315 |
| format | Article |
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Unsaturated polyester (UPE) resins are used in a variety of thermosetting applications due to the reduced cost when compared to epoxy resins; however, UPE resins also have reduced thermomechanical performance. Investigating avenues to improve the performance of UPEs has led to the use of bio‐based starting materials as structural components of the synthesized prepolymers as a result of their advantageous structural features. Isosorbide, a compound derived from renewable feedstocks, has been utilized to provide additional stiffness from the diol component for novel unsaturated polyesters resins. These resins have been shown to possess Tg's (32−72°C) and storage moduli (540−2200 MPa) that are in the desired range for composite materials with viscosities (1.2−25 Pa s) amenable to a variety of liquid molding techniques. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42315.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.42315</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Blackwell Publishing Ltd</publisher><subject>biopolymers and renewable polymers ; Diols ; Liquids ; Materials science ; Polyester resins ; polyesters ; Polymers ; Prepolymers ; Resins ; thermosets ; Thermosetting resins ; Unsaturated</subject><ispartof>Journal of applied polymer science, 2015-08, Vol.132 (30), p.np-n/a</ispartof><rights>2015 Wiley Periodicals, Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4715-4025114da858c33cbd9c983005b80f3ca190666ed956c239c43b48e0fc549b9f3</citedby><cites>FETCH-LOGICAL-c4715-4025114da858c33cbd9c983005b80f3ca190666ed956c239c43b48e0fc549b9f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.42315$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.42315$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Sadler, Joshua M.</creatorcontrib><creatorcontrib>Toulan, Faye R.</creatorcontrib><creatorcontrib>Palmese, Giuseppe R.</creatorcontrib><creatorcontrib>La Scala, John J.</creatorcontrib><title>Unsaturated polyester resins for thermoset applications using renewable isosorbide as a component for property improvement</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>ABSTRACT
Unsaturated polyester (UPE) resins are used in a variety of thermosetting applications due to the reduced cost when compared to epoxy resins; however, UPE resins also have reduced thermomechanical performance. Investigating avenues to improve the performance of UPEs has led to the use of bio‐based starting materials as structural components of the synthesized prepolymers as a result of their advantageous structural features. Isosorbide, a compound derived from renewable feedstocks, has been utilized to provide additional stiffness from the diol component for novel unsaturated polyesters resins. These resins have been shown to possess Tg's (32−72°C) and storage moduli (540−2200 MPa) that are in the desired range for composite materials with viscosities (1.2−25 Pa s) amenable to a variety of liquid molding techniques. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42315.</description><subject>biopolymers and renewable polymers</subject><subject>Diols</subject><subject>Liquids</subject><subject>Materials science</subject><subject>Polyester resins</subject><subject>polyesters</subject><subject>Polymers</subject><subject>Prepolymers</subject><subject>Resins</subject><subject>thermosets</subject><subject>Thermosetting resins</subject><subject>Unsaturated</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqFkc1u1DAUhS1UJKaFBW9giQ1dZGrHP7GX7ajTVpqWkaBiaTnODbgkcWonlOHpcTvAohJidS2d75yr64PQW0qWlJDyxI7jkpeMihdoQYmuCi5LdYAWWaOF0lq8Qocp3RFCqSBygX7eDslOc7QTNHgM3Q7SBBFHSH5IuA0RT18h9iHBhHN2552dfMjSnIEvmRvgwdYdYJ9CCrH2DWCbsMUu9GMYYJieQsYYRojTDvs-P79Dn4XX6GVruwRvfs8jdLs-_7S6LDYfLq5Wp5vC8YqKgpNSUMobq4RyjLm60U4rRoioFWmZs1QTKSU0WkhXMu04q7kC0jrBda1bdoTe73Pz5vs532d6nxx0nR0gzMnQiggiqlLx_6NSl0wwIWhG3z1D78Ich3xIpiqthOZMZup4T7kYUorQmjH63sadocQ8Fmbyp5qnwjJ7smcffAe7f4PmdLv94yj2Dp9L-_HXYeM3IytWCfP55sJsz9Yf6fZmZa7ZL3rAqCk</recordid><startdate>20150810</startdate><enddate>20150810</enddate><creator>Sadler, Joshua M.</creator><creator>Toulan, Faye R.</creator><creator>Palmese, Giuseppe R.</creator><creator>La Scala, John J.</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>7SU</scope><scope>C1K</scope><scope>FR3</scope><scope>7ST</scope><scope>7U6</scope></search><sort><creationdate>20150810</creationdate><title>Unsaturated polyester resins for thermoset applications using renewable isosorbide as a component for property improvement</title><author>Sadler, Joshua M. ; Toulan, Faye R. ; Palmese, Giuseppe R. ; La Scala, John J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4715-4025114da858c33cbd9c983005b80f3ca190666ed956c239c43b48e0fc549b9f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>biopolymers and renewable polymers</topic><topic>Diols</topic><topic>Liquids</topic><topic>Materials science</topic><topic>Polyester resins</topic><topic>polyesters</topic><topic>Polymers</topic><topic>Prepolymers</topic><topic>Resins</topic><topic>thermosets</topic><topic>Thermosetting resins</topic><topic>Unsaturated</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sadler, Joshua M.</creatorcontrib><creatorcontrib>Toulan, Faye R.</creatorcontrib><creatorcontrib>Palmese, Giuseppe R.</creatorcontrib><creatorcontrib>La Scala, John J.</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Environmental Engineering Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Environment Abstracts</collection><collection>Sustainability Science Abstracts</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sadler, Joshua M.</au><au>Toulan, Faye R.</au><au>Palmese, Giuseppe R.</au><au>La Scala, John J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Unsaturated polyester resins for thermoset applications using renewable isosorbide as a component for property improvement</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2015-08-10</date><risdate>2015</risdate><volume>132</volume><issue>30</issue><spage>np</spage><epage>n/a</epage><pages>np-n/a</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>ABSTRACT
Unsaturated polyester (UPE) resins are used in a variety of thermosetting applications due to the reduced cost when compared to epoxy resins; however, UPE resins also have reduced thermomechanical performance. Investigating avenues to improve the performance of UPEs has led to the use of bio‐based starting materials as structural components of the synthesized prepolymers as a result of their advantageous structural features. Isosorbide, a compound derived from renewable feedstocks, has been utilized to provide additional stiffness from the diol component for novel unsaturated polyesters resins. These resins have been shown to possess Tg's (32−72°C) and storage moduli (540−2200 MPa) that are in the desired range for composite materials with viscosities (1.2−25 Pa s) amenable to a variety of liquid molding techniques. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42315.</abstract><cop>Hoboken</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/app.42315</doi><tpages>11</tpages></addata></record> |
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| source | Wiley Online Library All Journals |
| subjects | biopolymers and renewable polymers Diols Liquids Materials science Polyester resins polyesters Polymers Prepolymers Resins thermosets Thermosetting resins Unsaturated |
| title | Unsaturated polyester resins for thermoset applications using renewable isosorbide as a component for property improvement |
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