Role of the Selective Contacts in the Performance of Lead Halide Perovskite Solar Cells
The effect of electron- and hole-selective contacts in the final cell performance of hybrid lead halide perovskite, CH3NH3PbI3, solar cells has been systematically analyzed by impedance spectroscopy. Complete cells with compact TiO2 and spiro-OMeTAD as electron- and hole-selective contacts have been...
Gespeichert in:
| Veröffentlicht in: | The journal of physical chemistry letters 2014-02, Vol.5 (4), p.680-685 |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 685 |
|---|---|
| container_issue | 4 |
| container_start_page | 680 |
| container_title | The journal of physical chemistry letters |
| container_volume | 5 |
| creator | Juarez-Perez, Emilio J Wuβler, Michael Fabregat-Santiago, Francisco Lakus-Wollny, Kerstin Mankel, Eric Mayer, Thomas Jaegermann, Wolfram Mora-Sero, Ivan |
| description | The effect of electron- and hole-selective contacts in the final cell performance of hybrid lead halide perovskite, CH3NH3PbI3, solar cells has been systematically analyzed by impedance spectroscopy. Complete cells with compact TiO2 and spiro-OMeTAD as electron- and hole-selective contacts have been compared with incomplete cells without one or both selective contacts to highlight the specific role of each contact. It has been described how selective contacts contribute to enhance the cell FF and how the hole-selective contact is mainly responsible for the high V oc in this kind of device. We have determined that the recombination rate is mainly governed by the selective contacts. This fact has important implication for the future optimization of perovskite solar cells. Finally, we have developed a method to analyze the results obtained, and it has been applied for three different electron-selecting materials: TiO2, ZnO, and CdS. |
| doi_str_mv | 10.1021/jz500059v |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1704349555</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1704349555</sourcerecordid><originalsourceid>FETCH-LOGICAL-a381t-7633573de27bb330a7e3f72089d0f460b9e778181e1182b6d8033e184d6a1a513</originalsourceid><addsrcrecordid>eNptkE9Lw0AQxRdRbK0e_AKSi6CH6Ew2m90cJagVCop_8Bg2yQRTk2zdTQr66Y1tLR48zcD7zWPeY-wY4QIhwMv5lwAAES932BjjUPkSldj9s4_YgXNzgCgGJffZKIgCCYpHY_b6aGryTOl1b-Q9UU15Vy3JS0zb6bxzXtWulAeypbGNbvMVPCNdeFNdV8VKMkv3XnXDvam19RKqa3fI9kpdOzrazAl7ubl-Tqb-7P72Lrma-Zor7HwZcS4kLyiQWcY5aEm8lAGouIAyjCCLSUqFCglRBVlUKOCcUIVFpFEL5BN2tvZdWPPRk-vSpnL58IFuyfQuRQkhD2MhxICer9HcGucslenCVo22nylC-tNjuu1xYE82tn3WULElf4sbgNM1oHOXzk1v2yHlP0bfx7V3sQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1704349555</pqid></control><display><type>article</type><title>Role of the Selective Contacts in the Performance of Lead Halide Perovskite Solar Cells</title><source>ACS Publications</source><creator>Juarez-Perez, Emilio J ; Wuβler, Michael ; Fabregat-Santiago, Francisco ; Lakus-Wollny, Kerstin ; Mankel, Eric ; Mayer, Thomas ; Jaegermann, Wolfram ; Mora-Sero, Ivan</creator><creatorcontrib>Juarez-Perez, Emilio J ; Wuβler, Michael ; Fabregat-Santiago, Francisco ; Lakus-Wollny, Kerstin ; Mankel, Eric ; Mayer, Thomas ; Jaegermann, Wolfram ; Mora-Sero, Ivan</creatorcontrib><description>The effect of electron- and hole-selective contacts in the final cell performance of hybrid lead halide perovskite, CH3NH3PbI3, solar cells has been systematically analyzed by impedance spectroscopy. Complete cells with compact TiO2 and spiro-OMeTAD as electron- and hole-selective contacts have been compared with incomplete cells without one or both selective contacts to highlight the specific role of each contact. It has been described how selective contacts contribute to enhance the cell FF and how the hole-selective contact is mainly responsible for the high V oc in this kind of device. We have determined that the recombination rate is mainly governed by the selective contacts. This fact has important implication for the future optimization of perovskite solar cells. Finally, we have developed a method to analyze the results obtained, and it has been applied for three different electron-selecting materials: TiO2, ZnO, and CdS.</description><identifier>ISSN: 1948-7185</identifier><identifier>EISSN: 1948-7185</identifier><identifier>DOI: 10.1021/jz500059v</identifier><identifier>PMID: 26270836</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>Energy Conversion and Storage; Energy and Charge Transport</subject><ispartof>The journal of physical chemistry letters, 2014-02, Vol.5 (4), p.680-685</ispartof><rights>Copyright © 2014 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a381t-7633573de27bb330a7e3f72089d0f460b9e778181e1182b6d8033e184d6a1a513</citedby><cites>FETCH-LOGICAL-a381t-7633573de27bb330a7e3f72089d0f460b9e778181e1182b6d8033e184d6a1a513</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jz500059v$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jz500059v$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26270836$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Juarez-Perez, Emilio J</creatorcontrib><creatorcontrib>Wuβler, Michael</creatorcontrib><creatorcontrib>Fabregat-Santiago, Francisco</creatorcontrib><creatorcontrib>Lakus-Wollny, Kerstin</creatorcontrib><creatorcontrib>Mankel, Eric</creatorcontrib><creatorcontrib>Mayer, Thomas</creatorcontrib><creatorcontrib>Jaegermann, Wolfram</creatorcontrib><creatorcontrib>Mora-Sero, Ivan</creatorcontrib><title>Role of the Selective Contacts in the Performance of Lead Halide Perovskite Solar Cells</title><title>The journal of physical chemistry letters</title><addtitle>J. Phys. Chem. Lett</addtitle><description>The effect of electron- and hole-selective contacts in the final cell performance of hybrid lead halide perovskite, CH3NH3PbI3, solar cells has been systematically analyzed by impedance spectroscopy. Complete cells with compact TiO2 and spiro-OMeTAD as electron- and hole-selective contacts have been compared with incomplete cells without one or both selective contacts to highlight the specific role of each contact. It has been described how selective contacts contribute to enhance the cell FF and how the hole-selective contact is mainly responsible for the high V oc in this kind of device. We have determined that the recombination rate is mainly governed by the selective contacts. This fact has important implication for the future optimization of perovskite solar cells. Finally, we have developed a method to analyze the results obtained, and it has been applied for three different electron-selecting materials: TiO2, ZnO, and CdS.</description><subject>Energy Conversion and Storage; Energy and Charge Transport</subject><issn>1948-7185</issn><issn>1948-7185</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNptkE9Lw0AQxRdRbK0e_AKSi6CH6Ew2m90cJagVCop_8Bg2yQRTk2zdTQr66Y1tLR48zcD7zWPeY-wY4QIhwMv5lwAAES932BjjUPkSldj9s4_YgXNzgCgGJffZKIgCCYpHY_b6aGryTOl1b-Q9UU15Vy3JS0zb6bxzXtWulAeypbGNbvMVPCNdeFNdV8VKMkv3XnXDvam19RKqa3fI9kpdOzrazAl7ubl-Tqb-7P72Lrma-Zor7HwZcS4kLyiQWcY5aEm8lAGouIAyjCCLSUqFCglRBVlUKOCcUIVFpFEL5BN2tvZdWPPRk-vSpnL58IFuyfQuRQkhD2MhxICer9HcGucslenCVo22nylC-tNjuu1xYE82tn3WULElf4sbgNM1oHOXzk1v2yHlP0bfx7V3sQ</recordid><startdate>20140220</startdate><enddate>20140220</enddate><creator>Juarez-Perez, Emilio J</creator><creator>Wuβler, Michael</creator><creator>Fabregat-Santiago, Francisco</creator><creator>Lakus-Wollny, Kerstin</creator><creator>Mankel, Eric</creator><creator>Mayer, Thomas</creator><creator>Jaegermann, Wolfram</creator><creator>Mora-Sero, Ivan</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20140220</creationdate><title>Role of the Selective Contacts in the Performance of Lead Halide Perovskite Solar Cells</title><author>Juarez-Perez, Emilio J ; Wuβler, Michael ; Fabregat-Santiago, Francisco ; Lakus-Wollny, Kerstin ; Mankel, Eric ; Mayer, Thomas ; Jaegermann, Wolfram ; Mora-Sero, Ivan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a381t-7633573de27bb330a7e3f72089d0f460b9e778181e1182b6d8033e184d6a1a513</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Energy Conversion and Storage; Energy and Charge Transport</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Juarez-Perez, Emilio J</creatorcontrib><creatorcontrib>Wuβler, Michael</creatorcontrib><creatorcontrib>Fabregat-Santiago, Francisco</creatorcontrib><creatorcontrib>Lakus-Wollny, Kerstin</creatorcontrib><creatorcontrib>Mankel, Eric</creatorcontrib><creatorcontrib>Mayer, Thomas</creatorcontrib><creatorcontrib>Jaegermann, Wolfram</creatorcontrib><creatorcontrib>Mora-Sero, Ivan</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>The journal of physical chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Juarez-Perez, Emilio J</au><au>Wuβler, Michael</au><au>Fabregat-Santiago, Francisco</au><au>Lakus-Wollny, Kerstin</au><au>Mankel, Eric</au><au>Mayer, Thomas</au><au>Jaegermann, Wolfram</au><au>Mora-Sero, Ivan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Role of the Selective Contacts in the Performance of Lead Halide Perovskite Solar Cells</atitle><jtitle>The journal of physical chemistry letters</jtitle><addtitle>J. Phys. Chem. Lett</addtitle><date>2014-02-20</date><risdate>2014</risdate><volume>5</volume><issue>4</issue><spage>680</spage><epage>685</epage><pages>680-685</pages><issn>1948-7185</issn><eissn>1948-7185</eissn><abstract>The effect of electron- and hole-selective contacts in the final cell performance of hybrid lead halide perovskite, CH3NH3PbI3, solar cells has been systematically analyzed by impedance spectroscopy. Complete cells with compact TiO2 and spiro-OMeTAD as electron- and hole-selective contacts have been compared with incomplete cells without one or both selective contacts to highlight the specific role of each contact. It has been described how selective contacts contribute to enhance the cell FF and how the hole-selective contact is mainly responsible for the high V oc in this kind of device. We have determined that the recombination rate is mainly governed by the selective contacts. This fact has important implication for the future optimization of perovskite solar cells. Finally, we have developed a method to analyze the results obtained, and it has been applied for three different electron-selecting materials: TiO2, ZnO, and CdS.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>26270836</pmid><doi>10.1021/jz500059v</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1948-7185 |
| ispartof | The journal of physical chemistry letters, 2014-02, Vol.5 (4), p.680-685 |
| issn | 1948-7185 1948-7185 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1704349555 |
| source | ACS Publications |
| subjects | Energy Conversion and Storage Energy and Charge Transport |
| title | Role of the Selective Contacts in the Performance of Lead Halide Perovskite Solar Cells |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-02T03%3A56%3A31IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Role%20of%20the%20Selective%20Contacts%20in%20the%20Performance%20of%20Lead%20Halide%20Perovskite%20Solar%20Cells&rft.jtitle=The%20journal%20of%20physical%20chemistry%20letters&rft.au=Juarez-Perez,%20Emilio%20J&rft.date=2014-02-20&rft.volume=5&rft.issue=4&rft.spage=680&rft.epage=685&rft.pages=680-685&rft.issn=1948-7185&rft.eissn=1948-7185&rft_id=info:doi/10.1021/jz500059v&rft_dat=%3Cproquest_cross%3E1704349555%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1704349555&rft_id=info:pmid/26270836&rfr_iscdi=true |