Vibrational Perturbations and Ligand–Layer Coupling in a Single Crystal of Au144(SC2H4Ph)60 Nanocluster

We have determined vibrational signatures and optical gap of the Au144(PET)60 (PET: phenylethylthiol, SC2H4Ph) nanocluster solvated in deuterated dichloromethane (DCM-D2, CD2Cl2) and in a single crystal. For crystals, solid-state 13C NMR and X-ray diffraction were also measured. A revised value of 2...

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Veröffentlicht in:	The journal of physical chemistry letters 2014-01, Vol.5 (2), p.387-392
Hauptverfasser:	Koivisto, Jaakko, Salorinne, Kirsi, Mustalahti, Satu, Lahtinen, Tanja, Malola, Sami, Häkkinen, Hannu, Pettersson, Mika
Format:	Artikel
Sprache:	eng
Schlagworte:	Spectroscopy, Photochemistry, and Excited States
Online-Zugang:	Volltext
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