Self-Organized Traveling Chemo-Hydrodynamic Fingers Triggered by a Chemical Oscillator

Self-Organized Traveling Chemo-Hydrodynamic Fingers Triggered by a Chemical Oscillator

Pulsatile chemo-hydrodynamic patterns due to a coupling between an oscillating chemical reaction and buoyancy-driven hydrodynamic flows can develop when two solutions of separate reactants of the Belousov–Zhabotinsky reaction are put in contact in the gravity field and conditions for chemical oscill...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:The journal of physical chemistry letters 2014-02, Vol.5 (3), p.413-418
Hauptverfasser: Escala, D. M, Budroni, M. A, Carballido-Landeira, J, De Wit, A, Muñuzuri, A. P
Format: Artikel
Sprache:eng
Schlagworte:
Liquids
Chemical and Dynamical Processes in Solution
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 418
container_issue 3
container_start_page 413
container_title The journal of physical chemistry letters
container_volume 5
creator Escala, D. M
Budroni, M. A
Carballido-Landeira, J
De Wit, A
Muñuzuri, A. P
description Pulsatile chemo-hydrodynamic patterns due to a coupling between an oscillating chemical reaction and buoyancy-driven hydrodynamic flows can develop when two solutions of separate reactants of the Belousov–Zhabotinsky reaction are put in contact in the gravity field and conditions for chemical oscillations are met in the contact zone. In regular oscillatory conditions, localized periodic changes in the concentration of intermediate species induce pulsatile density gradients, which, in turn, generate traveling convective fingers breaking the transverse symmetry. These patterns are the self-organized result of a genuine coupling between chemical and hydrodynamic modes.
doi_str_mv 10.1021/jz402625z
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1704343524</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1704343524</sourcerecordid><originalsourceid>FETCH-LOGICAL-a315t-a2626fd918855f9cec6fb7aa6b5249ef4dce63391ca67f25f9b8659adbd6e5da3</originalsourceid><addsrcrecordid>eNpt0M9LwzAUB_AgipvTg_-A9CLooZq0TdoeZTgnDHZwei2vycvM6I-ZrEL31xvdHB485RE-fHnvS8glo3eMRux-tU1oJCK-PSJDlidZmLKMH_-ZB-TMuRWlIqdZekoGHqeCZ8mQvL1gpcO5XUJjtqiChYVPrEyzDMbvWLfhtFe2VX0DtZHBxP-jdR6ZpR88L_sAfqSRUAVzJ01Vwaa15-REQ-XwYv-OyOvkcTGehrP50_P4YRZCzPgmBL-I0CpnWca5ziVKocsUQJQ8SnLUiZIo4jhnEkSqI0_KTPAcVKkEcgXxiNzscte2_ejQbYraOIl-iQbbzhUspUmcxD7N09sdlbZ1zqIu1tbUYPuC0eK7xuJQo7dX-9iurFEd5G9vHlzvAEhXrNrONv7Kf4K-AO-Tem0</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1704343524</pqid></control><display><type>article</type><title>Self-Organized Traveling Chemo-Hydrodynamic Fingers Triggered by a Chemical Oscillator</title><source>American Chemical Society Journals</source><creator>Escala, D. M ; Budroni, M. A ; Carballido-Landeira, J ; De Wit, A ; Muñuzuri, A. P</creator><creatorcontrib>Escala, D. M ; Budroni, M. A ; Carballido-Landeira, J ; De Wit, A ; Muñuzuri, A. P</creatorcontrib><description>Pulsatile chemo-hydrodynamic patterns due to a coupling between an oscillating chemical reaction and buoyancy-driven hydrodynamic flows can develop when two solutions of separate reactants of the Belousov–Zhabotinsky reaction are put in contact in the gravity field and conditions for chemical oscillations are met in the contact zone. In regular oscillatory conditions, localized periodic changes in the concentration of intermediate species induce pulsatile density gradients, which, in turn, generate traveling convective fingers breaking the transverse symmetry. These patterns are the self-organized result of a genuine coupling between chemical and hydrodynamic modes.</description><identifier>ISSN: 1948-7185</identifier><identifier>EISSN: 1948-7185</identifier><identifier>DOI: 10.1021/jz402625z</identifier><identifier>PMID: 26276584</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>Liquids; Chemical and Dynamical Processes in Solution</subject><ispartof>The journal of physical chemistry letters, 2014-02, Vol.5 (3), p.413-418</ispartof><rights>Copyright © 2014 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a315t-a2626fd918855f9cec6fb7aa6b5249ef4dce63391ca67f25f9b8659adbd6e5da3</citedby><cites>FETCH-LOGICAL-a315t-a2626fd918855f9cec6fb7aa6b5249ef4dce63391ca67f25f9b8659adbd6e5da3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jz402625z$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jz402625z$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26276584$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Escala, D. M</creatorcontrib><creatorcontrib>Budroni, M. A</creatorcontrib><creatorcontrib>Carballido-Landeira, J</creatorcontrib><creatorcontrib>De Wit, A</creatorcontrib><creatorcontrib>Muñuzuri, A. P</creatorcontrib><title>Self-Organized Traveling Chemo-Hydrodynamic Fingers Triggered by a Chemical Oscillator</title><title>The journal of physical chemistry letters</title><addtitle>J. Phys. Chem. Lett</addtitle><description>Pulsatile chemo-hydrodynamic patterns due to a coupling between an oscillating chemical reaction and buoyancy-driven hydrodynamic flows can develop when two solutions of separate reactants of the Belousov–Zhabotinsky reaction are put in contact in the gravity field and conditions for chemical oscillations are met in the contact zone. In regular oscillatory conditions, localized periodic changes in the concentration of intermediate species induce pulsatile density gradients, which, in turn, generate traveling convective fingers breaking the transverse symmetry. These patterns are the self-organized result of a genuine coupling between chemical and hydrodynamic modes.</description><subject>Liquids; Chemical and Dynamical Processes in Solution</subject><issn>1948-7185</issn><issn>1948-7185</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNpt0M9LwzAUB_AgipvTg_-A9CLooZq0TdoeZTgnDHZwei2vycvM6I-ZrEL31xvdHB485RE-fHnvS8glo3eMRux-tU1oJCK-PSJDlidZmLKMH_-ZB-TMuRWlIqdZekoGHqeCZ8mQvL1gpcO5XUJjtqiChYVPrEyzDMbvWLfhtFe2VX0DtZHBxP-jdR6ZpR88L_sAfqSRUAVzJ01Vwaa15-REQ-XwYv-OyOvkcTGehrP50_P4YRZCzPgmBL-I0CpnWca5ziVKocsUQJQ8SnLUiZIo4jhnEkSqI0_KTPAcVKkEcgXxiNzscte2_ejQbYraOIl-iQbbzhUspUmcxD7N09sdlbZ1zqIu1tbUYPuC0eK7xuJQo7dX-9iurFEd5G9vHlzvAEhXrNrONv7Kf4K-AO-Tem0</recordid><startdate>20140206</startdate><enddate>20140206</enddate><creator>Escala, D. M</creator><creator>Budroni, M. A</creator><creator>Carballido-Landeira, J</creator><creator>De Wit, A</creator><creator>Muñuzuri, A. P</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20140206</creationdate><title>Self-Organized Traveling Chemo-Hydrodynamic Fingers Triggered by a Chemical Oscillator</title><author>Escala, D. M ; Budroni, M. A ; Carballido-Landeira, J ; De Wit, A ; Muñuzuri, A. P</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a315t-a2626fd918855f9cec6fb7aa6b5249ef4dce63391ca67f25f9b8659adbd6e5da3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Liquids; Chemical and Dynamical Processes in Solution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Escala, D. M</creatorcontrib><creatorcontrib>Budroni, M. A</creatorcontrib><creatorcontrib>Carballido-Landeira, J</creatorcontrib><creatorcontrib>De Wit, A</creatorcontrib><creatorcontrib>Muñuzuri, A. P</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>The journal of physical chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Escala, D. M</au><au>Budroni, M. A</au><au>Carballido-Landeira, J</au><au>De Wit, A</au><au>Muñuzuri, A. P</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Self-Organized Traveling Chemo-Hydrodynamic Fingers Triggered by a Chemical Oscillator</atitle><jtitle>The journal of physical chemistry letters</jtitle><addtitle>J. Phys. Chem. Lett</addtitle><date>2014-02-06</date><risdate>2014</risdate><volume>5</volume><issue>3</issue><spage>413</spage><epage>418</epage><pages>413-418</pages><issn>1948-7185</issn><eissn>1948-7185</eissn><abstract>Pulsatile chemo-hydrodynamic patterns due to a coupling between an oscillating chemical reaction and buoyancy-driven hydrodynamic flows can develop when two solutions of separate reactants of the Belousov–Zhabotinsky reaction are put in contact in the gravity field and conditions for chemical oscillations are met in the contact zone. In regular oscillatory conditions, localized periodic changes in the concentration of intermediate species induce pulsatile density gradients, which, in turn, generate traveling convective fingers breaking the transverse symmetry. These patterns are the self-organized result of a genuine coupling between chemical and hydrodynamic modes.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>26276584</pmid><doi>10.1021/jz402625z</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1948-7185
ispartof The journal of physical chemistry letters, 2014-02, Vol.5 (3), p.413-418
issn 1948-7185
1948-7185
language eng
recordid cdi_proquest_miscellaneous_1704343524
source American Chemical Society Journals
subjects Liquids
Chemical and Dynamical Processes in Solution
title Self-Organized Traveling Chemo-Hydrodynamic Fingers Triggered by a Chemical Oscillator
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-27T18%3A23%3A10IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Self-Organized%20Traveling%20Chemo-Hydrodynamic%20Fingers%20Triggered%20by%20a%20Chemical%20Oscillator&rft.jtitle=The%20journal%20of%20physical%20chemistry%20letters&rft.au=Escala,%20D.%20M&rft.date=2014-02-06&rft.volume=5&rft.issue=3&rft.spage=413&rft.epage=418&rft.pages=413-418&rft.issn=1948-7185&rft.eissn=1948-7185&rft_id=info:doi/10.1021/jz402625z&rft_dat=%3Cproquest_cross%3E1704343524%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1704343524&rft_id=info:pmid/26276584&rfr_iscdi=true