Stereospecific Intramolecular Reductive Cross-Electrophile Coupling Reactions for Cyclopropane Synthesis

The stereo­specific reductive cross-electro­phile coupling reaction of 2-aryl-4-chloro­tetra­hydro­pyrans to afford disubstituted cyclo­propanes is reported. This ring contraction presents surprises with respect to the stereo­chemical outcome of reaction of the alkyl halide moiety. While cross-coupl...

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Veröffentlicht in:	Journal of the American Chemical Society 2015-08, Vol.137 (31), p.9760-9763
Hauptverfasser:	Tollefson, Emily J, Erickson, Lucas W, Jarvo, Elizabeth R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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