A Near-Infrared-Emissive Alkynyl-Protected Au24 Nanocluster

An alkynyl‐protected gold nanocluster [Au24(CCPh)14(PPh3)4](SbF6)2 has been prepared by a direct reduction method. Single‐crystal X‐ray diffraction reveals that the molecular structure contains a Au22 core that is made of two Au13‐centered cuboctahedra that share a square face. Two staple‐like PhC...

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Veröffentlicht in:	Angewandte Chemie International Edition 2015-08, Vol.54 (33), p.9683-9686
Hauptverfasser:	Wan, Xian-Kai, Xu, Wen Wu, Yuan, Shang-Fu, Gao, Yi, Zeng, Xiao-Cheng, Wang, Quan-Ming
Format:	Artikel
Sprache:	eng
Schlagworte:	alkyne ligands cluster compounds Crystals DFT calculations Diffraction gold photophysics
Online-Zugang:	Volltext
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