Selective Monoarylation of Primary Amines Using the Pd-PEPPSI-IPent(Cl) Precatalyst

A single set of reaction conditions for the palladium-catalyzed amination of a wide variety of (hetero)aryl halides using primary alkyl amines has been developed. By combining the exceptionally high reactivity of the Pd-PEPPSI-IPent(Cl) catalyst (PEPPSI=pyridine enhanced precatalyst preparation, sta...

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Veröffentlicht in:	Angewandte Chemie International Edition 2015-08, Vol.54 (33), p.9507-9511
Hauptverfasser:	Sharif, Sepideh, Rucker, Richard P, Chandrasoma, Nalin, Mitchell, David, Rodriguez, Michael J, Froese, Robert D J, Organ, Michael G
Format:	Artikel
Sprache:	eng
Schlagworte:	Amination Amines - chemistry Butylated Hydroxytoluene - analogs & derivatives Butylated Hydroxytoluene - chemistry Catalysis Halogens - chemistry Hydrocarbons, Aromatic - chemistry Palladium - chemistry Pyridines - chemistry
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