σ-Accepting Properties of a Chlorobismuthine Ligand
BiZness as usual? Not exactly! The bismuth atom of the tridentate diphosphinobismuthine (o‐(Ph2P)C6H4)2BiCl behaves as a Z rather than L ligand when in the coordination sphere of late transition metals such as gold. The σ‐acceptor behavior of Bi is supported by its disphenoid coordination geometry a...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2012-05, Vol.51 (20), p.4985-4988 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Lin, Tzu-Pin Ke, Iou-Sheng Gabbaï, François P. |
| description | BiZness as usual? Not exactly! The bismuth atom of the tridentate diphosphinobismuthine (o‐(Ph2P)C6H4)2BiCl behaves as a Z rather than L ligand when in the coordination sphere of late transition metals such as gold. The σ‐acceptor behavior of Bi is supported by its disphenoid coordination geometry and theoretical studies, which show a Au→Bi interaction. |
| doi_str_mv | 10.1002/anie.201200854 |
| format | Article |
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| language | eng |
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| source | Wiley Online Library All Journals |
| subjects | Bismuth Gold hypervalence Lewis acids Ligands palladium Transition metals |
| title | σ-Accepting Properties of a Chlorobismuthine Ligand |
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