Iron Pincer Complex Catalyzed, Environmentally Benign, E-Selective Semi-Hydrogenation of Alkynes

Ironing out hydrogenation: For the first time, an iron catalyst provided chemo‐ and stereo‐selective semi‐hydrogenation of alkynes to E‐alkenes. This efficient, atom‐economical reaction is catalyzed by a novel acridine‐based PNP iron pincer catalyst and exhibits excellent functional group tolerance...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie International Edition 2013-12, Vol.52 (52), p.14131-14134
Hauptverfasser:	Srimani, Dipankar, Diskin-Posner, Yael, Ben-David, Yehoshoa, Milstein, David
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes Catalysts Drawing and ironing Functional groups homogeneous catalysis Hydrogenation Iron iron pincer complex stereoselectivity Tolerances
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	14134
container_issue	52
container_start_page	14131
container_title	Angewandte Chemie International Edition
container_volume	52
creator	Srimani, Dipankar Diskin-Posner, Yael Ben-David, Yehoshoa Milstein, David
description	Ironing out hydrogenation: For the first time, an iron catalyst provided chemo‐ and stereo‐selective semi‐hydrogenation of alkynes to E‐alkenes. This efficient, atom‐economical reaction is catalyzed by a novel acridine‐based PNP iron pincer catalyst and exhibits excellent functional group tolerance under mild, neutral, environmentally benign reaction conditions.
doi_str_mv	10.1002/anie.201306629
format	Article
fullrecord	<record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1701123288</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3159708111</sourcerecordid><originalsourceid>FETCH-LOGICAL-c5479-b3c3267b3f1abfa84eecb9c589a4721723ff11f1303938b7a7d09e089f295673</originalsourceid><addsrcrecordid>eNqFkcFv0zAUhy0EYmNw5YgiceFAiu2XxPGxRGUrqsakVeJonPR58uY4xU7Hwl-Pq44KcdnJ1tP3Pun9foS8ZXTGKOWftLc445QBrSoun5FTVnKWgxDwPP0LgFzUJTshr2K8TXxd0-olOeEFlMABTsmPZRh8dmV9hyFrhn7r8CFr9Kjd9Bs3H7OFv7eJ6NGnkZuyz-jtjU_z_BoddqO9x-wae5tfTJsw3KDXo03CwWRzdzd5jK_JC6NdxDeP7xlZf1msm4t89e182cxXeVcWQuYtdMAr0YJhujW6LhC7VnZlLXUhOBMcjGHMpDtBQt0KLTZUIq2l4bKsBJyRDwftNgw_dxhH1dvYoXPa47CLignKGIcUwNNoIWkKjcLe-v4_9HbYBZ_uSFRVywJoKRM1O1BdGGIMaNQ22F6HSTGq9i2pfUvq2FJaePeo3bU9bo7431oSIA_AL-twekKn5pfLxb_y_LBr44gPx10d7lTKSZTq--W5WjVfr9YrKtQa_gBYHKvn</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1468943059</pqid></control><display><type>article</type><title>Iron Pincer Complex Catalyzed, Environmentally Benign, E-Selective Semi-Hydrogenation of Alkynes</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Srimani, Dipankar ; Diskin-Posner, Yael ; Ben-David, Yehoshoa ; Milstein, David</creator><creatorcontrib>Srimani, Dipankar ; Diskin-Posner, Yael ; Ben-David, Yehoshoa ; Milstein, David</creatorcontrib><description>Ironing out hydrogenation: For the first time, an iron catalyst provided chemo‐ and stereo‐selective semi‐hydrogenation of alkynes to E‐alkenes. This efficient, atom‐economical reaction is catalyzed by a novel acridine‐based PNP iron pincer catalyst and exhibits excellent functional group tolerance under mild, neutral, environmentally benign reaction conditions.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201306629</identifier><identifier>PMID: 24353233</identifier><identifier>CODEN: ACIEAY</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Alkynes ; Catalysts ; Drawing and ironing ; Functional groups ; homogeneous catalysis ; Hydrogenation ; Iron ; iron pincer complex ; stereoselectivity ; Tolerances</subject><ispartof>Angewandte Chemie International Edition, 2013-12, Vol.52 (52), p.14131-14134</ispartof><rights>Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5479-b3c3267b3f1abfa84eecb9c589a4721723ff11f1303938b7a7d09e089f295673</citedby><cites>FETCH-LOGICAL-c5479-b3c3267b3f1abfa84eecb9c589a4721723ff11f1303938b7a7d09e089f295673</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201306629$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201306629$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24353233$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Srimani, Dipankar</creatorcontrib><creatorcontrib>Diskin-Posner, Yael</creatorcontrib><creatorcontrib>Ben-David, Yehoshoa</creatorcontrib><creatorcontrib>Milstein, David</creatorcontrib><title>Iron Pincer Complex Catalyzed, Environmentally Benign, E-Selective Semi-Hydrogenation of Alkynes</title><title>Angewandte Chemie International Edition</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>Ironing out hydrogenation: For the first time, an iron catalyst provided chemo‐ and stereo‐selective semi‐hydrogenation of alkynes to E‐alkenes. This efficient, atom‐economical reaction is catalyzed by a novel acridine‐based PNP iron pincer catalyst and exhibits excellent functional group tolerance under mild, neutral, environmentally benign reaction conditions.</description><subject>Alkynes</subject><subject>Catalysts</subject><subject>Drawing and ironing</subject><subject>Functional groups</subject><subject>homogeneous catalysis</subject><subject>Hydrogenation</subject><subject>Iron</subject><subject>iron pincer complex</subject><subject>stereoselectivity</subject><subject>Tolerances</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqFkcFv0zAUhy0EYmNw5YgiceFAiu2XxPGxRGUrqsakVeJonPR58uY4xU7Hwl-Pq44KcdnJ1tP3Pun9foS8ZXTGKOWftLc445QBrSoun5FTVnKWgxDwPP0LgFzUJTshr2K8TXxd0-olOeEFlMABTsmPZRh8dmV9hyFrhn7r8CFr9Kjd9Bs3H7OFv7eJ6NGnkZuyz-jtjU_z_BoddqO9x-wae5tfTJsw3KDXo03CwWRzdzd5jK_JC6NdxDeP7xlZf1msm4t89e182cxXeVcWQuYtdMAr0YJhujW6LhC7VnZlLXUhOBMcjGHMpDtBQt0KLTZUIq2l4bKsBJyRDwftNgw_dxhH1dvYoXPa47CLignKGIcUwNNoIWkKjcLe-v4_9HbYBZ_uSFRVywJoKRM1O1BdGGIMaNQ22F6HSTGq9i2pfUvq2FJaePeo3bU9bo7431oSIA_AL-twekKn5pfLxb_y_LBr44gPx10d7lTKSZTq--W5WjVfr9YrKtQa_gBYHKvn</recordid><startdate>20131223</startdate><enddate>20131223</enddate><creator>Srimani, Dipankar</creator><creator>Diskin-Posner, Yael</creator><creator>Ben-David, Yehoshoa</creator><creator>Milstein, David</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20131223</creationdate><title>Iron Pincer Complex Catalyzed, Environmentally Benign, E-Selective Semi-Hydrogenation of Alkynes</title><author>Srimani, Dipankar ; Diskin-Posner, Yael ; Ben-David, Yehoshoa ; Milstein, David</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5479-b3c3267b3f1abfa84eecb9c589a4721723ff11f1303938b7a7d09e089f295673</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Alkynes</topic><topic>Catalysts</topic><topic>Drawing and ironing</topic><topic>Functional groups</topic><topic>homogeneous catalysis</topic><topic>Hydrogenation</topic><topic>Iron</topic><topic>iron pincer complex</topic><topic>stereoselectivity</topic><topic>Tolerances</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Srimani, Dipankar</creatorcontrib><creatorcontrib>Diskin-Posner, Yael</creatorcontrib><creatorcontrib>Ben-David, Yehoshoa</creatorcontrib><creatorcontrib>Milstein, David</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Srimani, Dipankar</au><au>Diskin-Posner, Yael</au><au>Ben-David, Yehoshoa</au><au>Milstein, David</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Iron Pincer Complex Catalyzed, Environmentally Benign, E-Selective Semi-Hydrogenation of Alkynes</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. Chem. Int. Ed</addtitle><date>2013-12-23</date><risdate>2013</risdate><volume>52</volume><issue>52</issue><spage>14131</spage><epage>14134</epage><pages>14131-14134</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><coden>ACIEAY</coden><abstract>Ironing out hydrogenation: For the first time, an iron catalyst provided chemo‐ and stereo‐selective semi‐hydrogenation of alkynes to E‐alkenes. This efficient, atom‐economical reaction is catalyzed by a novel acridine‐based PNP iron pincer catalyst and exhibits excellent functional group tolerance under mild, neutral, environmentally benign reaction conditions.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>24353233</pmid><doi>10.1002/anie.201306629</doi><tpages>4</tpages><edition>International ed. in English</edition></addata></record>
fulltext	fulltext
identifier	ISSN: 1433-7851
ispartof	Angewandte Chemie International Edition, 2013-12, Vol.52 (52), p.14131-14134
issn	1433-7851 1521-3773
language	eng
recordid	cdi_proquest_miscellaneous_1701123288
source	Wiley Online Library Journals Frontfile Complete
subjects	Alkynes Catalysts Drawing and ironing Functional groups homogeneous catalysis Hydrogenation Iron iron pincer complex stereoselectivity Tolerances
title	Iron Pincer Complex Catalyzed, Environmentally Benign, E-Selective Semi-Hydrogenation of Alkynes
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-13T13%3A50%3A53IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Iron%20Pincer%20Complex%20Catalyzed,%20Environmentally%20Benign,%20E-Selective%20Semi-Hydrogenation%20of%20Alkynes&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.au=Srimani,%20Dipankar&rft.date=2013-12-23&rft.volume=52&rft.issue=52&rft.spage=14131&rft.epage=14134&rft.pages=14131-14134&rft.issn=1433-7851&rft.eissn=1521-3773&rft.coden=ACIEAY&rft_id=info:doi/10.1002/anie.201306629&rft_dat=%3Cproquest_cross%3E3159708111%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1468943059&rft_id=info:pmid/24353233&rfr_iscdi=true