Intramolecular Metal-Free Oxidative Aryl-Aryl Coupling: An Unusual Hypervalent-Iodine-Mediated Rearrangement of 2-Substituted N-Phenylbenzamides

Hypervalent‐iodine‐mediated oxidative coupling of the two aryl groups in either 2‐acylamino‐N‐phenyl‐benzamides or 2‐hydroxy‐N‐phenylbenzamides, with concomitant insertion of the ortho‐substituted N or O atom into the tether, has been described for the first time. This unusual metal‐free rearrangeme...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Angewandte Chemie International Edition 2014-06, Vol.53 (24), p.6216-6219
Hauptverfasser:	Shang, Siyun, Zhang-Negrerie, Daisy, Du, Yunfei, Zhao, Kang
Format:	Artikel
Sprache:	eng
Schlagworte:	Acids, Heterocyclic - chemistry Aromatic compounds Bonding Catalysis Cleavage cross-coupling heterocycles hypervalent iodine reagents Insertion Joining Molecular Structure Oxidation-Reduction rearrangement Tethers
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!