Continuous-Flow Oxidative Cyanation of Primary and Secondary Amines Using Singlet Oxygen

Primary and secondary amines can be rapidly and quantitatively oxidized to the corresponding imines by singlet oxygen. This reactive form of oxygen was produced using a variable‐temperature continuous‐flow LED‐photoreactor with a catalytic amount of tetraphenylporphyrin as the sensitizer. α‐Aminonit...

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Veröffentlicht in:	Angewandte Chemie International Edition 2014-01, Vol.53 (2), p.557-561
Hauptverfasser:	Ushakov, Dmitry B., Gilmore, Kerry, Kopetzki, Daniel, McQuade, D. Tyler, Seeberger, Peter H.
Format:	Artikel
Sprache:	eng
Schlagworte:	Amines Amines - chemistry Amino acids Cyanides Cyanides - chemistry CH activation flow chemistry Imines Imines - chemistry Joining Molecular Structure Nitriles - chemical synthesis Nitriles - chemistry Oxidation-Reduction Photochemistry photooxidation Porphyrins - chemistry Precursors Singlet oxygen Singlet Oxygen - chemistry Strecker reaction Synthesis
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