Carbon Dioxide as a C sub(1) Building Block for the Formation of Carboxylic Acids by Formal Catalytic Hydrocarboxylation

Carbon Dioxide as a C sub(1) Building Block for the Formation of Carboxylic Acids by Formal Catalytic Hydrocarboxylation

A happy marriage of two processes: An effective catalytic system was identified for the direct synthesis of carboxylic acids from non-activated olefins or alcohols, CO sub(2), and H sub(2). Detailed analysis together with labeling studies indicated that the overall hydrocarboxylation of simple olefi...

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Veröffentlicht in:Angewandte Chemie International Edition 2013-11, Vol.52 (46), p.12119-12123
Hauptverfasser: Ostapowicz, Thomas G, Schmitz, Marc, Krystof, Monika, Klankermayer, Juergen, Leitner, Walter
Format: Artikel
Sprache:eng
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Carbon dioxide
Carboxylic acids
Catalysis
Catalysts
Formations
Olefins
Rhodium
Synthesis
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container_end_page 12123
container_issue 46
container_start_page 12119
container_title Angewandte Chemie International Edition
container_volume 52
creator Ostapowicz, Thomas G
Schmitz, Marc
Krystof, Monika
Klankermayer, Juergen
Leitner, Walter
description A happy marriage of two processes: An effective catalytic system was identified for the direct synthesis of carboxylic acids from non-activated olefins or alcohols, CO sub(2), and H sub(2). Detailed analysis together with labeling studies indicated that the overall hydrocarboxylation of simple olefins results from a combination of the reverse water-gas shift (rWGS) reaction and a hydroxycarbonylation step, each promoted by a rhodium catalyst (see scheme).
doi_str_mv 10.1002/anie.201304529
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subjects Carbon dioxide
Carboxylic acids
Catalysis
Catalysts
Formations
Olefins
Rhodium
Synthesis
title Carbon Dioxide as a C sub(1) Building Block for the Formation of Carboxylic Acids by Formal Catalytic Hydrocarboxylation
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