Highly Efficient CH Hydroxylation of Carbonyl Compounds with Oxygen under Mild Conditions

A transition‐metal‐free Cs2CO3‐catalyzed α‐hydroxylation of carbonyl compounds with O2 as the oxygen source is described. This reaction provides an efficient approach to tertiary α‐hydroxycarbonyl compounds, which are highly valued chemicals and widely used in the chemical and pharmaceutical industr...

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Veröffentlicht in:	Angewandte Chemie International Edition 2014-01, Vol.53 (2), p.548-552
Hauptverfasser:	Liang, Yu-Feng, Jiao, Ning
Format:	Artikel
Sprache:	eng
Schlagworte:	Bonding Carbamates - chemical synthesis Carbamates - chemistry Carbonyl compounds Catalysis cesium Cleavage CH functionalization dioxygen Hydrogen Bonding Hydroxylation Molecular Structure Oxidants Oxidizing agents Oxygen - chemistry oxygenation Pharmaceuticals Transformations
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