Synthesis of Gold Square-like Plates from Ultrathin Gold Square Sheets: The Evolution of Structure Phase and Shape

It's hip to be square: Gold square‐like plates exhibit alternating hexagonal close‐packed (hcp, see picture, yellow) and face‐centered cubic (fcc, red) structures in the center and defect‐free fcc structures at one pair of the opposite thick edges. They can be synthesized from Au square sheets...

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Veröffentlicht in:Angewandte Chemie International Edition 2011-12, Vol.50 (51), p.12245-12248
Hauptverfasser: Huang, Xiao, Li, Hai, Li, Shaozhou, Wu, Shixin, Boey, Freddy, Ma, Jan, Zhang, Hua
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container_issue 51
container_start_page 12245
container_title Angewandte Chemie International Edition
container_volume 50
creator Huang, Xiao
Li, Hai
Li, Shaozhou
Wu, Shixin
Boey, Freddy
Ma, Jan
Zhang, Hua
description It's hip to be square: Gold square‐like plates exhibit alternating hexagonal close‐packed (hcp, see picture, yellow) and face‐centered cubic (fcc, red) structures in the center and defect‐free fcc structures at one pair of the opposite thick edges. They can be synthesized from Au square sheets in a secondary growth process. For the first time, the hcp‐to‐fcc phase transformation associated with shape variation in Au nanostructures is demonstrated.
doi_str_mv 10.1002/anie.201105850
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subjects Close packed lattices
Evolution
Face centered cubic lattice
fcc structures
Gold
hcp structures
Hexagonal cells
Nanostructure
phase transformation
Phase transformations
Plates (structural members)
Synthesis
template synthesis
title Synthesis of Gold Square-like Plates from Ultrathin Gold Square Sheets: The Evolution of Structure Phase and Shape
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