Stereospecific Carbene Polymerization with Oxygenated Rh(diene) Species
Breath‐taking activation: Stereoregular carbene polymerization proceeds via cationic [(allyl)RhIII–polymeryl]+ species. These are most efficiently generated by oxygenation of the [(diene)RhI] precatalysts, which involves an unusual rearrangement of 2‐rhodaoxetane intermediates. This discovery gives...
Gespeichert in:
| Veröffentlicht in: | Angewandte Chemie International Edition 2012-05, Vol.51 (21), p.5157-5161 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 5161 |
|---|---|
| container_issue | 21 |
| container_start_page | 5157 |
| container_title | Angewandte Chemie International Edition |
| container_volume | 51 |
| creator | Walters, Annemarie J. C. Troeppner, Oliver Ivanović-Burmazović, Ivana Tejel, Cristina del Río, M. Pilar Reek, Joost N. H. de Bruin, Bas |
| description | Breath‐taking activation: Stereoregular carbene polymerization proceeds via cationic [(allyl)RhIII–polymeryl]+ species. These are most efficiently generated by oxygenation of the [(diene)RhI] precatalysts, which involves an unusual rearrangement of 2‐rhodaoxetane intermediates. This discovery gives detailed insight in the reaction mechanism. |
| doi_str_mv | 10.1002/anie.201200069 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1701110288</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1701110288</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4849-2197731625f94f07a930764a795c72d698b9f34097e419e36c7ee4ad88aba0553</originalsourceid><addsrcrecordid>eNqFkUtLAzEUhYMoPqpblzLgRhdT85o8llK1FoqKVXQX0pk7Gp3O1GSK1l9vSrWIGyFws_jO4d5zENonuEswpie2dtClmFCMsdBraJtklKRMSrYe_5yxVKqMbKGdEF4irxQWm2iLUq41pXob9UcteGjCFHJXujzpWT-GGpKbpppPwLtP27qmTt5d-5xcf8yfoLYtFMnt81HhInecjBZKCLtoo7RVgL3v2UH3F-d3vct0eN0f9E6Hac4V1yklOq5GBM1KzUssrWZYCm6lznJJC6HVWJeMYy2BEw1M5BKA20IpO7Y4y1gHHS19p755m0FozcSFHKrK1tDMgiESE0IWh_6PYsJJfEJE9PAP-tLMfB0PMTHDGDRWikequ6Ry34TgoTRT7ybWz6OVWbRhFm2YVRtRcPBtOxtPoFjhP_FHQC-Bd1fB_B87c3o1OP9tni61LrTwsdJa_2qEZDIzD1d9o4bDm7NHysyIfQE_sqJ6</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1431000884</pqid></control><display><type>article</type><title>Stereospecific Carbene Polymerization with Oxygenated Rh(diene) Species</title><source>MEDLINE</source><source>Wiley Online Library All Journals</source><creator>Walters, Annemarie J. C. ; Troeppner, Oliver ; Ivanović-Burmazović, Ivana ; Tejel, Cristina ; del Río, M. Pilar ; Reek, Joost N. H. ; de Bruin, Bas</creator><creatorcontrib>Walters, Annemarie J. C. ; Troeppner, Oliver ; Ivanović-Burmazović, Ivana ; Tejel, Cristina ; del Río, M. Pilar ; Reek, Joost N. H. ; de Bruin, Bas</creatorcontrib><description>Breath‐taking activation: Stereoregular carbene polymerization proceeds via cationic [(allyl)RhIII–polymeryl]+ species. These are most efficiently generated by oxygenation of the [(diene)RhI] precatalysts, which involves an unusual rearrangement of 2‐rhodaoxetane intermediates. This discovery gives detailed insight in the reaction mechanism.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201200069</identifier><identifier>PMID: 22499229</identifier><identifier>CODEN: ACIEAY</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Activation ; Aluminum base alloys ; Carbenes ; Cationic ; diazo compounds ; Mass Spectrometry ; oxidation ; Oxygen - chemistry ; Oxygenated ; Oxygenation ; Polymerization ; Polymers - chemistry ; Reaction mechanisms ; rhodium ; Rhodium - chemistry ; Stereoisomerism</subject><ispartof>Angewandte Chemie International Edition, 2012-05, Vol.51 (21), p.5157-5161</ispartof><rights>Copyright © 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4849-2197731625f94f07a930764a795c72d698b9f34097e419e36c7ee4ad88aba0553</citedby><cites>FETCH-LOGICAL-c4849-2197731625f94f07a930764a795c72d698b9f34097e419e36c7ee4ad88aba0553</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201200069$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201200069$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/22499229$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Walters, Annemarie J. C.</creatorcontrib><creatorcontrib>Troeppner, Oliver</creatorcontrib><creatorcontrib>Ivanović-Burmazović, Ivana</creatorcontrib><creatorcontrib>Tejel, Cristina</creatorcontrib><creatorcontrib>del Río, M. Pilar</creatorcontrib><creatorcontrib>Reek, Joost N. H.</creatorcontrib><creatorcontrib>de Bruin, Bas</creatorcontrib><title>Stereospecific Carbene Polymerization with Oxygenated Rh(diene) Species</title><title>Angewandte Chemie International Edition</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>Breath‐taking activation: Stereoregular carbene polymerization proceeds via cationic [(allyl)RhIII–polymeryl]+ species. These are most efficiently generated by oxygenation of the [(diene)RhI] precatalysts, which involves an unusual rearrangement of 2‐rhodaoxetane intermediates. This discovery gives detailed insight in the reaction mechanism.</description><subject>Activation</subject><subject>Aluminum base alloys</subject><subject>Carbenes</subject><subject>Cationic</subject><subject>diazo compounds</subject><subject>Mass Spectrometry</subject><subject>oxidation</subject><subject>Oxygen - chemistry</subject><subject>Oxygenated</subject><subject>Oxygenation</subject><subject>Polymerization</subject><subject>Polymers - chemistry</subject><subject>Reaction mechanisms</subject><subject>rhodium</subject><subject>Rhodium - chemistry</subject><subject>Stereoisomerism</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkUtLAzEUhYMoPqpblzLgRhdT85o8llK1FoqKVXQX0pk7Gp3O1GSK1l9vSrWIGyFws_jO4d5zENonuEswpie2dtClmFCMsdBraJtklKRMSrYe_5yxVKqMbKGdEF4irxQWm2iLUq41pXob9UcteGjCFHJXujzpWT-GGpKbpppPwLtP27qmTt5d-5xcf8yfoLYtFMnt81HhInecjBZKCLtoo7RVgL3v2UH3F-d3vct0eN0f9E6Hac4V1yklOq5GBM1KzUssrWZYCm6lznJJC6HVWJeMYy2BEw1M5BKA20IpO7Y4y1gHHS19p755m0FozcSFHKrK1tDMgiESE0IWh_6PYsJJfEJE9PAP-tLMfB0PMTHDGDRWikequ6Ry34TgoTRT7ybWz6OVWbRhFm2YVRtRcPBtOxtPoFjhP_FHQC-Bd1fB_B87c3o1OP9tni61LrTwsdJa_2qEZDIzD1d9o4bDm7NHysyIfQE_sqJ6</recordid><startdate>20120521</startdate><enddate>20120521</enddate><creator>Walters, Annemarie J. C.</creator><creator>Troeppner, Oliver</creator><creator>Ivanović-Burmazović, Ivana</creator><creator>Tejel, Cristina</creator><creator>del Río, M. Pilar</creator><creator>Reek, Joost N. H.</creator><creator>de Bruin, Bas</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><scope>7QF</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20120521</creationdate><title>Stereospecific Carbene Polymerization with Oxygenated Rh(diene) Species</title><author>Walters, Annemarie J. C. ; Troeppner, Oliver ; Ivanović-Burmazović, Ivana ; Tejel, Cristina ; del Río, M. Pilar ; Reek, Joost N. H. ; de Bruin, Bas</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4849-2197731625f94f07a930764a795c72d698b9f34097e419e36c7ee4ad88aba0553</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Activation</topic><topic>Aluminum base alloys</topic><topic>Carbenes</topic><topic>Cationic</topic><topic>diazo compounds</topic><topic>Mass Spectrometry</topic><topic>oxidation</topic><topic>Oxygen - chemistry</topic><topic>Oxygenated</topic><topic>Oxygenation</topic><topic>Polymerization</topic><topic>Polymers - chemistry</topic><topic>Reaction mechanisms</topic><topic>rhodium</topic><topic>Rhodium - chemistry</topic><topic>Stereoisomerism</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Walters, Annemarie J. C.</creatorcontrib><creatorcontrib>Troeppner, Oliver</creatorcontrib><creatorcontrib>Ivanović-Burmazović, Ivana</creatorcontrib><creatorcontrib>Tejel, Cristina</creatorcontrib><creatorcontrib>del Río, M. Pilar</creatorcontrib><creatorcontrib>Reek, Joost N. H.</creatorcontrib><creatorcontrib>de Bruin, Bas</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>Aluminium Industry Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Walters, Annemarie J. C.</au><au>Troeppner, Oliver</au><au>Ivanović-Burmazović, Ivana</au><au>Tejel, Cristina</au><au>del Río, M. Pilar</au><au>Reek, Joost N. H.</au><au>de Bruin, Bas</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Stereospecific Carbene Polymerization with Oxygenated Rh(diene) Species</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. Chem. Int. Ed</addtitle><date>2012-05-21</date><risdate>2012</risdate><volume>51</volume><issue>21</issue><spage>5157</spage><epage>5161</epage><pages>5157-5161</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><coden>ACIEAY</coden><abstract>Breath‐taking activation: Stereoregular carbene polymerization proceeds via cationic [(allyl)RhIII–polymeryl]+ species. These are most efficiently generated by oxygenation of the [(diene)RhI] precatalysts, which involves an unusual rearrangement of 2‐rhodaoxetane intermediates. This discovery gives detailed insight in the reaction mechanism.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>22499229</pmid><doi>10.1002/anie.201200069</doi><tpages>5</tpages><edition>International ed. in English</edition><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie International Edition, 2012-05, Vol.51 (21), p.5157-5161 |
| issn | 1433-7851 1521-3773 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1701110288 |
| source | MEDLINE; Wiley Online Library All Journals |
| subjects | Activation Aluminum base alloys Carbenes Cationic diazo compounds Mass Spectrometry oxidation Oxygen - chemistry Oxygenated Oxygenation Polymerization Polymers - chemistry Reaction mechanisms rhodium Rhodium - chemistry Stereoisomerism |
| title | Stereospecific Carbene Polymerization with Oxygenated Rh(diene) Species |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-08T01%3A37%3A28IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Stereospecific%20Carbene%20Polymerization%20with%20Oxygenated%20Rh(diene)%20Species&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.au=Walters,%20Annemarie%20J.%20C.&rft.date=2012-05-21&rft.volume=51&rft.issue=21&rft.spage=5157&rft.epage=5161&rft.pages=5157-5161&rft.issn=1433-7851&rft.eissn=1521-3773&rft.coden=ACIEAY&rft_id=info:doi/10.1002/anie.201200069&rft_dat=%3Cproquest_cross%3E1701110288%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1431000884&rft_id=info:pmid/22499229&rfr_iscdi=true |