[Cr super(III) sub(8)M super(II) sub(6)] super(12+) Coordination Cubes (M super(II)=Cu,Co)
[Cr super(III) sub(8)M super(II) sub(6)] super(12+) (M super(II)=Cu, Co) coordination cubes were constructed from a simple [Cr super(III)L sub(3)] metalloligand and a "naked" M super(II) salt. The flexibility in the design proffers the potential to tune the physical properties, as all the...
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| Veröffentlicht in: | Angewandte Chemie 2015-06, Vol.127 (23), p.6865-6868 |
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| container_issue | 23 |
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| container_title | Angewandte Chemie |
| container_volume | 127 |
| creator | Sanz, Sergio O'Connor, Helen M Pineda, Eufemio Moreno Pedersen, Kasper S Nichol, Gary S Moensted, Ole Weihe, Hoegni Piligkos, Stergios McInnes, Eric JL Lusby, Paul J Brechin, Euan K |
| description | [Cr super(III) sub(8)M super(II) sub(6)] super(12+) (M super(II)=Cu, Co) coordination cubes were constructed from a simple [Cr super(III)L sub(3)] metalloligand and a "naked" M super(II) salt. The flexibility in the design proffers the potential to tune the physical properties, as all the constituent parts of the cage can be changed without structural alteration. Computational techniques (known in theoretical nuclear physics as statistical spectroscopy) in tandem with EPR spectroscopy are used to interpret the magnetic behavior.Original Abstract: Wie die Wuerfel fallen: [Cr super(III) sub(8)M super(II) sub(6)] super(12+)-Wuerfel (M=Cu, Co) wurden aus einem einfachen [Cr super(III)L sub(3)]-Metallo liganden und einem [ldquor]nackten" M super(II)-Salz hergestellt. Die physikalischen Eigenschaften lassen sich ohne daraus resultierende Strukturaenderung durch Austausch aller Kaefigbestandteile beeinflussen. Statistische und EPR-Spektroskopie wurden fuer die Interpretation des magnetischen Verhaltens verwendet. |
| doi_str_mv | 10.1002/ange.201501041 |
| format | Article |
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The flexibility in the design proffers the potential to tune the physical properties, as all the constituent parts of the cage can be changed without structural alteration. Computational techniques (known in theoretical nuclear physics as statistical spectroscopy) in tandem with EPR spectroscopy are used to interpret the magnetic behavior.Original Abstract: Wie die Wuerfel fallen: [Cr super(III) sub(8)M super(II) sub(6)] super(12+)-Wuerfel (M=Cu, Co) wurden aus einem einfachen [Cr super(III)L sub(3)]-Metallo liganden und einem [ldquor]nackten" M super(II)-Salz hergestellt. Die physikalischen Eigenschaften lassen sich ohne daraus resultierende Strukturaenderung durch Austausch aller Kaefigbestandteile beeinflussen. Statistische und EPR-Spektroskopie wurden fuer die Interpretation des magnetischen Verhaltens verwendet.</description><identifier>ISSN: 0044-8249</identifier><identifier>EISSN: 1521-3757</identifier><identifier>DOI: 10.1002/ange.201501041</identifier><language>eng</language><subject>Alterations ; Cage ; Construction ; Cubes ; Flexibility ; Nuclear physics ; Physical properties ; Spectroscopy</subject><ispartof>Angewandte Chemie, 2015-06, Vol.127 (23), p.6865-6868</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Sanz, Sergio</creatorcontrib><creatorcontrib>O'Connor, Helen M</creatorcontrib><creatorcontrib>Pineda, Eufemio Moreno</creatorcontrib><creatorcontrib>Pedersen, Kasper S</creatorcontrib><creatorcontrib>Nichol, Gary S</creatorcontrib><creatorcontrib>Moensted, Ole</creatorcontrib><creatorcontrib>Weihe, Hoegni</creatorcontrib><creatorcontrib>Piligkos, Stergios</creatorcontrib><creatorcontrib>McInnes, Eric JL</creatorcontrib><creatorcontrib>Lusby, Paul J</creatorcontrib><creatorcontrib>Brechin, Euan K</creatorcontrib><title>[Cr super(III) sub(8)M super(II) sub(6)] super(12+) Coordination Cubes (M super(II)=Cu,Co)</title><title>Angewandte Chemie</title><description>[Cr super(III) sub(8)M super(II) sub(6)] super(12+) (M super(II)=Cu, Co) coordination cubes were constructed from a simple [Cr super(III)L sub(3)] metalloligand and a "naked" M super(II) salt. The flexibility in the design proffers the potential to tune the physical properties, as all the constituent parts of the cage can be changed without structural alteration. Computational techniques (known in theoretical nuclear physics as statistical spectroscopy) in tandem with EPR spectroscopy are used to interpret the magnetic behavior.Original Abstract: Wie die Wuerfel fallen: [Cr super(III) sub(8)M super(II) sub(6)] super(12+)-Wuerfel (M=Cu, Co) wurden aus einem einfachen [Cr super(III)L sub(3)]-Metallo liganden und einem [ldquor]nackten" M super(II)-Salz hergestellt. Die physikalischen Eigenschaften lassen sich ohne daraus resultierende Strukturaenderung durch Austausch aller Kaefigbestandteile beeinflussen. 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The flexibility in the design proffers the potential to tune the physical properties, as all the constituent parts of the cage can be changed without structural alteration. Computational techniques (known in theoretical nuclear physics as statistical spectroscopy) in tandem with EPR spectroscopy are used to interpret the magnetic behavior.Original Abstract: Wie die Wuerfel fallen: [Cr super(III) sub(8)M super(II) sub(6)] super(12+)-Wuerfel (M=Cu, Co) wurden aus einem einfachen [Cr super(III)L sub(3)]-Metallo liganden und einem [ldquor]nackten" M super(II)-Salz hergestellt. Die physikalischen Eigenschaften lassen sich ohne daraus resultierende Strukturaenderung durch Austausch aller Kaefigbestandteile beeinflussen. Statistische und EPR-Spektroskopie wurden fuer die Interpretation des magnetischen Verhaltens verwendet.</abstract><doi>10.1002/ange.201501041</doi></addata></record> |
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| identifier | ISSN: 0044-8249 |
| ispartof | Angewandte Chemie, 2015-06, Vol.127 (23), p.6865-6868 |
| issn | 0044-8249 1521-3757 |
| language | eng |
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| source | Wiley Online Library All Journals |
| subjects | Alterations Cage Construction Cubes Flexibility Nuclear physics Physical properties Spectroscopy |
| title | [Cr super(III) sub(8)M super(II) sub(6)] super(12+) Coordination Cubes (M super(II)=Cu,Co) |
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