Short and Sweet: D-Glucose to L-Glucuronic Acid and L-Glucose

The scarcity and expense of access to L-sugars and other rare sugars have prevented the exploitation of their biological potential; for example D-psicose, only recently available, has been recognized as an important new food. Here we give the definitive and cheap synthesis of 99.4% pure L-glucose fr...

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Veröffentlicht in:	Angewandte Chemie 2014-01, Vol.126 (4), p.1179-1182
Hauptverfasser:	Martinez, RFernando, Liu, Zilei, Glawar, Andreas FG, Yoshihara, Akihide, Izumori, Ken, Fleet, George WJ, Jenkinson, Sarah F
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystallization Expenses Foods Purification Recognition Solvents Sweets Synthesis
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creator	Martinez, RFernando Liu, Zilei Glawar, Andreas FG Yoshihara, Akihide Izumori, Ken Fleet, George WJ Jenkinson, Sarah F
description	The scarcity and expense of access to L-sugars and other rare sugars have prevented the exploitation of their biological potential; for example D-psicose, only recently available, has been recognized as an important new food. Here we give the definitive and cheap synthesis of 99.4% pure L-glucose from D-glucose which requires purification of neither intermediates nor final product other than extraction into and removal of solvents; a simple crystallization will raise the purity to >99.8%.
doi_str_mv	10.1002/ange.201309073
format	Article
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source	Wiley Journals
subjects	Crystallization Expenses Foods Purification Recognition Solvents Sweets Synthesis
title	Short and Sweet: D-Glucose to L-Glucuronic Acid and L-Glucose
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