pH-Dependent Proton Conducting Behavior in a Metal-Organic Framework Material

A porous metal–organic framework (MOF), [Ni2(dobdc)(H2O)2]⋅6 H2O (Ni2(dobdc) or Ni‐MOF‐74; dobdc4−=2,5‐dioxido‐1,4‐benzenedicarboxylate) with hexagonal channels was synthesized using a microwave‐assisted solvothermal reaction. Soaking Ni2(dobdc) in sulfuric acid solutions at different pH values affo...

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Veröffentlicht in:	Angewandte Chemie International Edition 2014-08, Vol.53 (32), p.8383-8387
Hauptverfasser:	Phang, Won Ju, Lee, Woo Ram, Yoo, Kicheon, Ryu, Dae Won, Kim, BongSoo, Hong, Chang Seop
Format:	Artikel
Sprache:	eng
Schlagworte:	Acidification Activation energy Channels Clusters Conduction Displays Metal-organic frameworks Porosity proton conducting materials protonated water clusters Relative humidity Sulfuric acid
Online-Zugang:	Volltext
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