Magnetic properties of anion-radical salt [FeII(dipy)3](TCNQ)4·(CH3)2CO
•Magnetic susceptibility temperature dependence of [FeII(dipy)3](TCNQ)4·(CH3)2CO.•Mössbauer spectra of [FeII(dipy)3](TCNQ)4·(CH3)2CO anion-radical salt.•Antiferromagnetic ordering in anion-radical TCNQ stack. Magnetic properties of anion-radical TCNQ salt [Fe(dipy)3](TCNQ)4·(CH3)2CO have been invest...
Gespeichert in:
| Veröffentlicht in: | Synthetic metals 2014-08, Vol.194, p.7-10 |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 10 |
|---|---|
| container_issue | |
| container_start_page | 7 |
| container_title | Synthetic metals |
| container_volume | 194 |
| creator | Vasylets, G. Starodub, V.A. Feher, A. Kajnakova, M. Zboril, R. Tucek, J. Metz, H. Potocnak, I. |
| description | •Magnetic susceptibility temperature dependence of [FeII(dipy)3](TCNQ)4·(CH3)2CO.•Mössbauer spectra of [FeII(dipy)3](TCNQ)4·(CH3)2CO anion-radical salt.•Antiferromagnetic ordering in anion-radical TCNQ stack.
Magnetic properties of anion-radical TCNQ salt [Fe(dipy)3](TCNQ)4·(CH3)2CO have been investigated (dipy is 2,2′-dipyridil). X-ray diffraction data allow presence of two types of TCNQ stacks: tetramerized (diamagnetic) and partly dimerized (paramagnetic). Due to Mössbauer spectroscopy data iron cation appears as two-valent ion in low-spin state. Magnetic susceptibility temperature dependence is described by Bonner–Fischer model with additional weak impurity paramagnetism. Susceptibility curve is in good qualitative agreement with ESR spectra. |
| doi_str_mv | 10.1016/j.synthmet.2014.04.011 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1701084840</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S037967791400143X</els_id><sourcerecordid>1701084840</sourcerecordid><originalsourceid>FETCH-LOGICAL-c375t-98c3e5fb6695aed149b310e56328f2bb0cec99c5c8be351f1f951f1e514f1b8a3</originalsourceid><addsrcrecordid>eNqFUMFqGzEQFaWBukl-IeylYB_W1Ugr7erWsiSxIU0IOKcQhFY7amXWu660DvjLcs-XVcZur4VhZg7vzZv3CLkCOgcK8ut6Hvf9-GuD45xRKOY0FcAHMoGqVDlnin4kE8rTLstSfSKfY1xTSkExMSGLH-Znj6O32TYMWwyjx5gNLjO9H_o8mNZb02XRdGP2fIPL5bT12_2Mv0xX9f3jrHh_m9YLPmP1wwU5c6aLeHma5-Tp5npVL_K7h9tl_f0ut7wUY64qy1G4RkolDLZQqIYDRSE5qxxrGmrRKmWFrRrkAhw4degooHDQVIafk-nxbvr39w7jqDc-Wuw60-OwixpKCrQqqoImqDxCbRhiDOj0NviNCXsNVB-i02v9Nzp9iE7TVACJ-OWkYWKy74LprY__2KwSkjEpE-7bEYfJ8KvHoKP12FtsfUA76nbw_5P6A-b5hq8</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1701084840</pqid></control><display><type>article</type><title>Magnetic properties of anion-radical salt [FeII(dipy)3](TCNQ)4·(CH3)2CO</title><source>Elsevier ScienceDirect Journals</source><creator>Vasylets, G. ; Starodub, V.A. ; Feher, A. ; Kajnakova, M. ; Zboril, R. ; Tucek, J. ; Metz, H. ; Potocnak, I.</creator><creatorcontrib>Vasylets, G. ; Starodub, V.A. ; Feher, A. ; Kajnakova, M. ; Zboril, R. ; Tucek, J. ; Metz, H. ; Potocnak, I.</creatorcontrib><description>•Magnetic susceptibility temperature dependence of [FeII(dipy)3](TCNQ)4·(CH3)2CO.•Mössbauer spectra of [FeII(dipy)3](TCNQ)4·(CH3)2CO anion-radical salt.•Antiferromagnetic ordering in anion-radical TCNQ stack.
Magnetic properties of anion-radical TCNQ salt [Fe(dipy)3](TCNQ)4·(CH3)2CO have been investigated (dipy is 2,2′-dipyridil). X-ray diffraction data allow presence of two types of TCNQ stacks: tetramerized (diamagnetic) and partly dimerized (paramagnetic). Due to Mössbauer spectroscopy data iron cation appears as two-valent ion in low-spin state. Magnetic susceptibility temperature dependence is described by Bonner–Fischer model with additional weak impurity paramagnetism. Susceptibility curve is in good qualitative agreement with ESR spectra.</description><identifier>ISSN: 0379-6779</identifier><identifier>EISSN: 1879-3290</identifier><identifier>DOI: 10.1016/j.synthmet.2014.04.011</identifier><identifier>CODEN: SYMEDZ</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Diamagnetism, paramagnetism and superparamagnetism ; Diffraction ; Exact sciences and technology ; Iron ; Magnetic permeability ; Magnetic properties ; Magnetic properties and materials ; Magnetic resonances and relaxations in condensed matter, mössbauer effect ; Magnetic susceptibility ; Magnetically ordered materials: other intrinsic properties ; Mathematical models ; Mossbauer spectroscopy ; Mössbauer effect; other γ-ray spectroscopy ; Mössbauer spectroscopy ; Physics ; Saturation moments and magnetic susceptibilities ; Spectra ; Tetracyanoquinodimethane ; X-rays</subject><ispartof>Synthetic metals, 2014-08, Vol.194, p.7-10</ispartof><rights>2014 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c375t-98c3e5fb6695aed149b310e56328f2bb0cec99c5c8be351f1f951f1e514f1b8a3</citedby><cites>FETCH-LOGICAL-c375t-98c3e5fb6695aed149b310e56328f2bb0cec99c5c8be351f1f951f1e514f1b8a3</cites><orcidid>0000-0001-8845-4709</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S037967791400143X$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28562266$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Vasylets, G.</creatorcontrib><creatorcontrib>Starodub, V.A.</creatorcontrib><creatorcontrib>Feher, A.</creatorcontrib><creatorcontrib>Kajnakova, M.</creatorcontrib><creatorcontrib>Zboril, R.</creatorcontrib><creatorcontrib>Tucek, J.</creatorcontrib><creatorcontrib>Metz, H.</creatorcontrib><creatorcontrib>Potocnak, I.</creatorcontrib><title>Magnetic properties of anion-radical salt [FeII(dipy)3](TCNQ)4·(CH3)2CO</title><title>Synthetic metals</title><description>•Magnetic susceptibility temperature dependence of [FeII(dipy)3](TCNQ)4·(CH3)2CO.•Mössbauer spectra of [FeII(dipy)3](TCNQ)4·(CH3)2CO anion-radical salt.•Antiferromagnetic ordering in anion-radical TCNQ stack.
Magnetic properties of anion-radical TCNQ salt [Fe(dipy)3](TCNQ)4·(CH3)2CO have been investigated (dipy is 2,2′-dipyridil). X-ray diffraction data allow presence of two types of TCNQ stacks: tetramerized (diamagnetic) and partly dimerized (paramagnetic). Due to Mössbauer spectroscopy data iron cation appears as two-valent ion in low-spin state. Magnetic susceptibility temperature dependence is described by Bonner–Fischer model with additional weak impurity paramagnetism. Susceptibility curve is in good qualitative agreement with ESR spectra.</description><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Diamagnetism, paramagnetism and superparamagnetism</subject><subject>Diffraction</subject><subject>Exact sciences and technology</subject><subject>Iron</subject><subject>Magnetic permeability</subject><subject>Magnetic properties</subject><subject>Magnetic properties and materials</subject><subject>Magnetic resonances and relaxations in condensed matter, mössbauer effect</subject><subject>Magnetic susceptibility</subject><subject>Magnetically ordered materials: other intrinsic properties</subject><subject>Mathematical models</subject><subject>Mossbauer spectroscopy</subject><subject>Mössbauer effect; other γ-ray spectroscopy</subject><subject>Mössbauer spectroscopy</subject><subject>Physics</subject><subject>Saturation moments and magnetic susceptibilities</subject><subject>Spectra</subject><subject>Tetracyanoquinodimethane</subject><subject>X-rays</subject><issn>0379-6779</issn><issn>1879-3290</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqFUMFqGzEQFaWBukl-IeylYB_W1Ugr7erWsiSxIU0IOKcQhFY7amXWu660DvjLcs-XVcZur4VhZg7vzZv3CLkCOgcK8ut6Hvf9-GuD45xRKOY0FcAHMoGqVDlnin4kE8rTLstSfSKfY1xTSkExMSGLH-Znj6O32TYMWwyjx5gNLjO9H_o8mNZb02XRdGP2fIPL5bT12_2Mv0xX9f3jrHh_m9YLPmP1wwU5c6aLeHma5-Tp5npVL_K7h9tl_f0ut7wUY64qy1G4RkolDLZQqIYDRSE5qxxrGmrRKmWFrRrkAhw4degooHDQVIafk-nxbvr39w7jqDc-Wuw60-OwixpKCrQqqoImqDxCbRhiDOj0NviNCXsNVB-i02v9Nzp9iE7TVACJ-OWkYWKy74LprY__2KwSkjEpE-7bEYfJ8KvHoKP12FtsfUA76nbw_5P6A-b5hq8</recordid><startdate>20140801</startdate><enddate>20140801</enddate><creator>Vasylets, G.</creator><creator>Starodub, V.A.</creator><creator>Feher, A.</creator><creator>Kajnakova, M.</creator><creator>Zboril, R.</creator><creator>Tucek, J.</creator><creator>Metz, H.</creator><creator>Potocnak, I.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-8845-4709</orcidid></search><sort><creationdate>20140801</creationdate><title>Magnetic properties of anion-radical salt [FeII(dipy)3](TCNQ)4·(CH3)2CO</title><author>Vasylets, G. ; Starodub, V.A. ; Feher, A. ; Kajnakova, M. ; Zboril, R. ; Tucek, J. ; Metz, H. ; Potocnak, I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c375t-98c3e5fb6695aed149b310e56328f2bb0cec99c5c8be351f1f951f1e514f1b8a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Diamagnetism, paramagnetism and superparamagnetism</topic><topic>Diffraction</topic><topic>Exact sciences and technology</topic><topic>Iron</topic><topic>Magnetic permeability</topic><topic>Magnetic properties</topic><topic>Magnetic properties and materials</topic><topic>Magnetic resonances and relaxations in condensed matter, mössbauer effect</topic><topic>Magnetic susceptibility</topic><topic>Magnetically ordered materials: other intrinsic properties</topic><topic>Mathematical models</topic><topic>Mossbauer spectroscopy</topic><topic>Mössbauer effect; other γ-ray spectroscopy</topic><topic>Mössbauer spectroscopy</topic><topic>Physics</topic><topic>Saturation moments and magnetic susceptibilities</topic><topic>Spectra</topic><topic>Tetracyanoquinodimethane</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vasylets, G.</creatorcontrib><creatorcontrib>Starodub, V.A.</creatorcontrib><creatorcontrib>Feher, A.</creatorcontrib><creatorcontrib>Kajnakova, M.</creatorcontrib><creatorcontrib>Zboril, R.</creatorcontrib><creatorcontrib>Tucek, J.</creatorcontrib><creatorcontrib>Metz, H.</creatorcontrib><creatorcontrib>Potocnak, I.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Synthetic metals</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vasylets, G.</au><au>Starodub, V.A.</au><au>Feher, A.</au><au>Kajnakova, M.</au><au>Zboril, R.</au><au>Tucek, J.</au><au>Metz, H.</au><au>Potocnak, I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Magnetic properties of anion-radical salt [FeII(dipy)3](TCNQ)4·(CH3)2CO</atitle><jtitle>Synthetic metals</jtitle><date>2014-08-01</date><risdate>2014</risdate><volume>194</volume><spage>7</spage><epage>10</epage><pages>7-10</pages><issn>0379-6779</issn><eissn>1879-3290</eissn><coden>SYMEDZ</coden><abstract>•Magnetic susceptibility temperature dependence of [FeII(dipy)3](TCNQ)4·(CH3)2CO.•Mössbauer spectra of [FeII(dipy)3](TCNQ)4·(CH3)2CO anion-radical salt.•Antiferromagnetic ordering in anion-radical TCNQ stack.
Magnetic properties of anion-radical TCNQ salt [Fe(dipy)3](TCNQ)4·(CH3)2CO have been investigated (dipy is 2,2′-dipyridil). X-ray diffraction data allow presence of two types of TCNQ stacks: tetramerized (diamagnetic) and partly dimerized (paramagnetic). Due to Mössbauer spectroscopy data iron cation appears as two-valent ion in low-spin state. Magnetic susceptibility temperature dependence is described by Bonner–Fischer model with additional weak impurity paramagnetism. Susceptibility curve is in good qualitative agreement with ESR spectra.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.synthmet.2014.04.011</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-8845-4709</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0379-6779 |
| ispartof | Synthetic metals, 2014-08, Vol.194, p.7-10 |
| issn | 0379-6779 1879-3290 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1701084840 |
| source | Elsevier ScienceDirect Journals |
| subjects | Condensed matter: electronic structure, electrical, magnetic, and optical properties Diamagnetism, paramagnetism and superparamagnetism Diffraction Exact sciences and technology Iron Magnetic permeability Magnetic properties Magnetic properties and materials Magnetic resonances and relaxations in condensed matter, mössbauer effect Magnetic susceptibility Magnetically ordered materials: other intrinsic properties Mathematical models Mossbauer spectroscopy Mössbauer effect other γ-ray spectroscopy Mössbauer spectroscopy Physics Saturation moments and magnetic susceptibilities Spectra Tetracyanoquinodimethane X-rays |
| title | Magnetic properties of anion-radical salt [FeII(dipy)3](TCNQ)4·(CH3)2CO |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-01T21%3A47%3A58IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Magnetic%20properties%20of%20anion-radical%20salt%20%5BFeII(dipy)3%5D(TCNQ)4%C2%B7(CH3)2CO&rft.jtitle=Synthetic%20metals&rft.au=Vasylets,%20G.&rft.date=2014-08-01&rft.volume=194&rft.spage=7&rft.epage=10&rft.pages=7-10&rft.issn=0379-6779&rft.eissn=1879-3290&rft.coden=SYMEDZ&rft_id=info:doi/10.1016/j.synthmet.2014.04.011&rft_dat=%3Cproquest_cross%3E1701084840%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1701084840&rft_id=info:pmid/&rft_els_id=S037967791400143X&rfr_iscdi=true |