Mathematical Modeling of 1,3-Butadiene and Methyl Methacrylate Emulsion Copolymerization Process

Mathematical Modeling of 1,3-Butadiene and Methyl Methacrylate Emulsion Copolymerization Process

A mathematical model for emulsion copolymerization process of 1,3-butadiene and methyl methacrylate is presented and validated with experimental data in a batch reactor. The model is able to explain the effects of changes in temperature, monomer-to-water ratio, emulsifier concentration, initiator co...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Industrial & engineering chemistry research 2014-05, Vol.53 (18), p.7343-7351
Hauptverfasser: Oliveira, Eder D., Casella, Esleide L., Araujo, Odair, Giudici, Reinaldo
Format: Artikel
Sprache:eng
Schlagworte:
Accounting
Concentration (composition)
Conversion
Copolymerization
Emulsions
Evolution
Mathematical models
Monomers
Polymethyl methacrylates
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 7351
container_issue 18
container_start_page 7343
container_title Industrial & engineering chemistry research
container_volume 53
creator Oliveira, Eder D.
Casella, Esleide L.
Araujo, Odair
Giudici, Reinaldo
description A mathematical model for emulsion copolymerization process of 1,3-butadiene and methyl methacrylate is presented and validated with experimental data in a batch reactor. The model is able to explain the effects of changes in temperature, monomer-to-water ratio, emulsifier concentration, initiator concentration, and monomer feed composition on the time evolution of monomer conversion, average particle size, and pressure. Despite its simplicity and a reduced number of adjustable parameters, the model is capable of accounting for the basic features of emulsion copolymerization processes and can be used in engineering applications.
doi_str_mv 10.1021/ie402990e
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1701079695</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1701079695</sourcerecordid><originalsourceid>FETCH-LOGICAL-a292t-774021cfc91d8d8f20d184d586eda1c65fe8580c40581ae17d26824166ebb86f3</originalsourceid><addsrcrecordid>eNptkD9PwzAUxC0EEqUw8A2yIIFE4D03TpwRqvJHagUDzMG1X6grJy52MpRPT6CIiemk00-nu2PsFOEKgeO1pQx4WQLtsREKDqmATOyzEUgpUyGlOGRHMa4BQIgsG7G3hepW1KjOauWShTfkbPue-DrBy0l623fKWGopUa1JFtSttu5HlA5bpzpKZk3vovVtMvUb77YNBfs5hA3Gc_CaYjxmB7VykU5-dcxe72Yv04d0_nT_OL2Zp4qXvEuLYuiNutYlGmlkzcGgzIyQORmFOhc1SSFBZyAkKsLC8FzyDPOclkuZ15MxO9_lboL_6Cl2VWOjJudUS76PFRaAUJR5KQb0Yofq4GMMVFebYBsVthVC9f1i9ffiwJ7tWKVjtfZ9aIcR_3Bf_ZBwyg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1701079695</pqid></control><display><type>article</type><title>Mathematical Modeling of 1,3-Butadiene and Methyl Methacrylate Emulsion Copolymerization Process</title><source>ACS_美国化学学会期刊（与NSTL共建）</source><creator>Oliveira, Eder D. ; Casella, Esleide L. ; Araujo, Odair ; Giudici, Reinaldo</creator><creatorcontrib>Oliveira, Eder D. ; Casella, Esleide L. ; Araujo, Odair ; Giudici, Reinaldo</creatorcontrib><description>A mathematical model for emulsion copolymerization process of 1,3-butadiene and methyl methacrylate is presented and validated with experimental data in a batch reactor. The model is able to explain the effects of changes in temperature, monomer-to-water ratio, emulsifier concentration, initiator concentration, and monomer feed composition on the time evolution of monomer conversion, average particle size, and pressure. Despite its simplicity and a reduced number of adjustable parameters, the model is capable of accounting for the basic features of emulsion copolymerization processes and can be used in engineering applications.</description><identifier>ISSN: 0888-5885</identifier><identifier>EISSN: 1520-5045</identifier><identifier>DOI: 10.1021/ie402990e</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>Accounting ; Concentration (composition) ; Conversion ; Copolymerization ; Emulsions ; Evolution ; Mathematical models ; Monomers ; Polymethyl methacrylates</subject><ispartof>Industrial &amp; engineering chemistry research, 2014-05, Vol.53 (18), p.7343-7351</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a292t-774021cfc91d8d8f20d184d586eda1c65fe8580c40581ae17d26824166ebb86f3</citedby><cites>FETCH-LOGICAL-a292t-774021cfc91d8d8f20d184d586eda1c65fe8580c40581ae17d26824166ebb86f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ie402990e$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ie402990e$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>315,781,785,2766,27078,27926,27927,56740,56790</link.rule.ids></links><search><creatorcontrib>Oliveira, Eder D.</creatorcontrib><creatorcontrib>Casella, Esleide L.</creatorcontrib><creatorcontrib>Araujo, Odair</creatorcontrib><creatorcontrib>Giudici, Reinaldo</creatorcontrib><title>Mathematical Modeling of 1,3-Butadiene and Methyl Methacrylate Emulsion Copolymerization Process</title><title>Industrial &amp; engineering chemistry research</title><addtitle>Ind. Eng. Chem. Res</addtitle><description>A mathematical model for emulsion copolymerization process of 1,3-butadiene and methyl methacrylate is presented and validated with experimental data in a batch reactor. The model is able to explain the effects of changes in temperature, monomer-to-water ratio, emulsifier concentration, initiator concentration, and monomer feed composition on the time evolution of monomer conversion, average particle size, and pressure. Despite its simplicity and a reduced number of adjustable parameters, the model is capable of accounting for the basic features of emulsion copolymerization processes and can be used in engineering applications.</description><subject>Accounting</subject><subject>Concentration (composition)</subject><subject>Conversion</subject><subject>Copolymerization</subject><subject>Emulsions</subject><subject>Evolution</subject><subject>Mathematical models</subject><subject>Monomers</subject><subject>Polymethyl methacrylates</subject><issn>0888-5885</issn><issn>1520-5045</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNptkD9PwzAUxC0EEqUw8A2yIIFE4D03TpwRqvJHagUDzMG1X6grJy52MpRPT6CIiemk00-nu2PsFOEKgeO1pQx4WQLtsREKDqmATOyzEUgpUyGlOGRHMa4BQIgsG7G3hepW1KjOauWShTfkbPue-DrBy0l623fKWGopUa1JFtSttu5HlA5bpzpKZk3vovVtMvUb77YNBfs5hA3Gc_CaYjxmB7VykU5-dcxe72Yv04d0_nT_OL2Zp4qXvEuLYuiNutYlGmlkzcGgzIyQORmFOhc1SSFBZyAkKsLC8FzyDPOclkuZ15MxO9_lboL_6Cl2VWOjJudUS76PFRaAUJR5KQb0Yofq4GMMVFebYBsVthVC9f1i9ffiwJ7tWKVjtfZ9aIcR_3Bf_ZBwyg</recordid><startdate>20140507</startdate><enddate>20140507</enddate><creator>Oliveira, Eder D.</creator><creator>Casella, Esleide L.</creator><creator>Araujo, Odair</creator><creator>Giudici, Reinaldo</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20140507</creationdate><title>Mathematical Modeling of 1,3-Butadiene and Methyl Methacrylate Emulsion Copolymerization Process</title><author>Oliveira, Eder D. ; Casella, Esleide L. ; Araujo, Odair ; Giudici, Reinaldo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a292t-774021cfc91d8d8f20d184d586eda1c65fe8580c40581ae17d26824166ebb86f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Accounting</topic><topic>Concentration (composition)</topic><topic>Conversion</topic><topic>Copolymerization</topic><topic>Emulsions</topic><topic>Evolution</topic><topic>Mathematical models</topic><topic>Monomers</topic><topic>Polymethyl methacrylates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Oliveira, Eder D.</creatorcontrib><creatorcontrib>Casella, Esleide L.</creatorcontrib><creatorcontrib>Araujo, Odair</creatorcontrib><creatorcontrib>Giudici, Reinaldo</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Industrial &amp; engineering chemistry research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Oliveira, Eder D.</au><au>Casella, Esleide L.</au><au>Araujo, Odair</au><au>Giudici, Reinaldo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mathematical Modeling of 1,3-Butadiene and Methyl Methacrylate Emulsion Copolymerization Process</atitle><jtitle>Industrial &amp; engineering chemistry research</jtitle><addtitle>Ind. Eng. Chem. Res</addtitle><date>2014-05-07</date><risdate>2014</risdate><volume>53</volume><issue>18</issue><spage>7343</spage><epage>7351</epage><pages>7343-7351</pages><issn>0888-5885</issn><eissn>1520-5045</eissn><abstract>A mathematical model for emulsion copolymerization process of 1,3-butadiene and methyl methacrylate is presented and validated with experimental data in a batch reactor. The model is able to explain the effects of changes in temperature, monomer-to-water ratio, emulsifier concentration, initiator concentration, and monomer feed composition on the time evolution of monomer conversion, average particle size, and pressure. Despite its simplicity and a reduced number of adjustable parameters, the model is capable of accounting for the basic features of emulsion copolymerization processes and can be used in engineering applications.</abstract><pub>American Chemical Society</pub><doi>10.1021/ie402990e</doi><tpages>9</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0888-5885
ispartof Industrial & engineering chemistry research, 2014-05, Vol.53 (18), p.7343-7351
issn 0888-5885
1520-5045
language eng
recordid cdi_proquest_miscellaneous_1701079695
source ACS_美国化学学会期刊（与NSTL共建）
subjects Accounting
Concentration (composition)
Conversion
Copolymerization
Emulsions
Evolution
Mathematical models
Monomers
Polymethyl methacrylates
title Mathematical Modeling of 1,3-Butadiene and Methyl Methacrylate Emulsion Copolymerization Process
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-17T20%3A53%3A31IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Mathematical%20Modeling%20of%201,3-Butadiene%20and%20Methyl%20Methacrylate%20Emulsion%20Copolymerization%20Process&rft.jtitle=Industrial%20&%20engineering%20chemistry%20research&rft.au=Oliveira,%20Eder%20D.&rft.date=2014-05-07&rft.volume=53&rft.issue=18&rft.spage=7343&rft.epage=7351&rft.pages=7343-7351&rft.issn=0888-5885&rft.eissn=1520-5045&rft_id=info:doi/10.1021/ie402990e&rft_dat=%3Cproquest_cross%3E1701079695%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1701079695&rft_id=info:pmid/&rfr_iscdi=true