Total Synthesis of CyrneineA

Total Synthesis of CyrneineA

Neuritogenic natural products: The tricyclic diterpene cyrneineA featuring a hexatrienal unit was prepared synthetically for the first time by a Heck reaction, a carbene ring expansion, and a reductive carbonylation. The structure of the natural product was assigned by X-ray crystal analysis of a sy...

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Veröffentlicht in:Angewandte Chemie International Edition 2012-04, Vol.51 (17), p.4071-4073
Hauptverfasser: Elamparuthi, Elangovan, Fellay, Cindy, Neuburger, Markus, Gademann, Karl
Format: Artikel
Sprache:eng
Schlagworte:
Carbenes
Carbonyls
Crystal structure
Natural products
Synthesis
X-rays
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creator Elamparuthi, Elangovan
Fellay, Cindy
Neuburger, Markus
Gademann, Karl
description Neuritogenic natural products: The tricyclic diterpene cyrneineA featuring a hexatrienal unit was prepared synthetically for the first time by a Heck reaction, a carbene ring expansion, and a reductive carbonylation. The structure of the natural product was assigned by X-ray crystal analysis of a synthetic sample.
doi_str_mv 10.1002/anie.201200515
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subjects Carbenes
Carbonyls
Crystal structure
Natural products
Synthesis
X-rays
title Total Synthesis of CyrneineA
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