Observation of Mode-Specific Vibrational Autodetachment from Dipole-Bound States of Cold Anions

Observation of Mode-Specific Vibrational Autodetachment from Dipole-Bound States of Cold Anions

Dipole‐bound states: Electron autodetachment of vibrationally excited dipole‐bound states of phenoxide anions is observed by photoelectron spectroscopy. The wave function of a dipole‐bound state and the observed normal modes are shown. The blue lobe of the orbital indicates that the electron is weak...

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Veröffentlicht in:Angewandte Chemie International Edition 2013-08, Vol.52 (34), p.8976-8979
Hauptverfasser: Liu, Hong-Tao, Ning, Chuan-Gang, Huang, Dao-Ling, Dau, Phuong Diem, Wang, Lai-Sheng
Format: Artikel
Sprache:eng
Schlagworte:
Anions
dipole-bound states
Dipoles
electron autodetachment
Excitation spectra
Lobes
Orbitals
phenoxides
Photoelectron spectroscopy
radicals
Wave functions
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Zusammenfassung:Dipole‐bound states: Electron autodetachment of vibrationally excited dipole‐bound states of phenoxide anions is observed by photoelectron spectroscopy. The wave function of a dipole‐bound state and the observed normal modes are shown. The blue lobe of the orbital indicates that the electron is weakly bound to the dipole.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201304695