An Unconventional Route to Hierarchically Ordered Block Copolymers on a Gradient Patterned Surface through Controlled Evaporative Self-Assembly

A chemically patterned surface was formed by controlled evaporative self‐assembly of concentric polymer stripes, followed by the removal of weakly deposited polymer, giving ultrathin polymer stripes with a width gradient on the Si substrate (see picture). A thin film of diblock copolymer hierarchica...

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Veröffentlicht in:Angewandte Chemie International Edition 2013-01, Vol.52 (4), p.1122-1127
Hauptverfasser: Byun, Myunghwan, Han, Wei, Li, Bo, Xin, Xukai, Lin, Zhiqun
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container_issue 4
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container_title Angewandte Chemie International Edition
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creator Byun, Myunghwan
Han, Wei
Li, Bo
Xin, Xukai
Lin, Zhiqun
description A chemically patterned surface was formed by controlled evaporative self‐assembly of concentric polymer stripes, followed by the removal of weakly deposited polymer, giving ultrathin polymer stripes with a width gradient on the Si substrate (see picture). A thin film of diblock copolymer hierarchically self‐assembled on the ultrathin polymer stripes, giving arrays of nanocylinders perpendicular to the surface of the film.
doi_str_mv 10.1002/anie.201208421
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subjects Arrays
Block copolymers
controlled evaporative self-assembly
Copolymers
Deposition
Evaporative
hierarchically ordered structures
Self assembly
Silicon substrates
surface patterning
Thin films
title An Unconventional Route to Hierarchically Ordered Block Copolymers on a Gradient Patterned Surface through Controlled Evaporative Self-Assembly
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