Simplifying Iron-Phosphine Catalysts for Cross-Coupling Reactions

Any old iron? Iron catalysts based on the widely available diphosphine ligand bis(diphenylphosphino)ethane have not previously fared particularly well in iron‐catalyzed cross‐coupling processes. However, this turns out not to be due to any inherently poor performance associated with the ligand, but...

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Veröffentlicht in:	Angewandte Chemie International Edition 2013-01, Vol.52 (4), p.1285-1288
Hauptverfasser:	Bedford, Robin B., Carter, Emma, Cogswell, Paul M., Gower, Nicholas J., Haddow, Mairi F., Harvey, Jeremy N., Murphy, Damien M., Neeve, Emily C., Nunn, Joshua
Format:	Artikel
Sprache:	eng
Schlagworte:	alkyl halides Catalysis Catalysts Coordination Complexes - chemistry cross-coupling Crystallography, X-Ray Formations Iron Iron - chemistry Ligands Molecular Conformation phosphine ligands Phosphines - chemistry
Online-Zugang:	Volltext
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