Oxidation of Methane to Methanol with Hydrogen Peroxide Using Supported Gold-Palladium Alloy Nanoparticles

Direct and selective: Supported gold–palladium nanoparticles are active for the oxidation of methane, giving a high selectivity for the formation of methyl hydroperoxide and methanol, using hydrogen peroxide as the oxidant (see picture). The optimal methanol selectivity is achieved by performing the...

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Veröffentlicht in:Angewandte Chemie International Edition 2013-01, Vol.52 (4), p.1280-1284
Hauptverfasser: Ab Rahim, Mohd Hasbi, Forde, Michael M., Jenkins, Robert L., Hammond, Ceri, He, Qian, Dimitratos, Nikolaos, Lopez-Sanchez, Jose Antonio, Carley, Albert F., Taylor, Stuart H., Willock, David J., Murphy, Damien M., Kiely, Christopher J., Hutchings, Graham J.
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container_end_page 1284
container_issue 4
container_start_page 1280
container_title Angewandte Chemie International Edition
container_volume 52
creator Ab Rahim, Mohd Hasbi
Forde, Michael M.
Jenkins, Robert L.
Hammond, Ceri
He, Qian
Dimitratos, Nikolaos
Lopez-Sanchez, Jose Antonio
Carley, Albert F.
Taylor, Stuart H.
Willock, David J.
Murphy, Damien M.
Kiely, Christopher J.
Hutchings, Graham J.
description Direct and selective: Supported gold–palladium nanoparticles are active for the oxidation of methane, giving a high selectivity for the formation of methyl hydroperoxide and methanol, using hydrogen peroxide as the oxidant (see picture). The optimal methanol selectivity is achieved by performing the reaction in the presence of hydrogen peroxide that has been generated in situ from hydrogen and oxygen.
doi_str_mv 10.1002/anie.201207717
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source Wiley Online Library Journals Frontfile Complete
subjects alloys
Formations
gold
Hydrogen peroxide
Methane
Methyl alcohol
Nanoparticles
Optimization
Oxidation
palladium
Selectivity
title Oxidation of Methane to Methanol with Hydrogen Peroxide Using Supported Gold-Palladium Alloy Nanoparticles
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