Oxidation of Methane to Methanol with Hydrogen Peroxide Using Supported Gold-Palladium Alloy Nanoparticles
Direct and selective: Supported gold–palladium nanoparticles are active for the oxidation of methane, giving a high selectivity for the formation of methyl hydroperoxide and methanol, using hydrogen peroxide as the oxidant (see picture). The optimal methanol selectivity is achieved by performing the...
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Veröffentlicht in: | Angewandte Chemie International Edition 2013-01, Vol.52 (4), p.1280-1284 |
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creator | Ab Rahim, Mohd Hasbi Forde, Michael M. Jenkins, Robert L. Hammond, Ceri He, Qian Dimitratos, Nikolaos Lopez-Sanchez, Jose Antonio Carley, Albert F. Taylor, Stuart H. Willock, David J. Murphy, Damien M. Kiely, Christopher J. Hutchings, Graham J. |
description | Direct and selective: Supported gold–palladium nanoparticles are active for the oxidation of methane, giving a high selectivity for the formation of methyl hydroperoxide and methanol, using hydrogen peroxide as the oxidant (see picture). The optimal methanol selectivity is achieved by performing the reaction in the presence of hydrogen peroxide that has been generated in situ from hydrogen and oxygen. |
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Chem. Int. Ed</addtitle><description>Direct and selective: Supported gold–palladium nanoparticles are active for the oxidation of methane, giving a high selectivity for the formation of methyl hydroperoxide and methanol, using hydrogen peroxide as the oxidant (see picture). The optimal methanol selectivity is achieved by performing the reaction in the presence of hydrogen peroxide that has been generated in situ from hydrogen and oxygen.</description><subject>alloys</subject><subject>Formations</subject><subject>gold</subject><subject>Hydrogen peroxide</subject><subject>Methane</subject><subject>Methyl alcohol</subject><subject>Nanoparticles</subject><subject>Optimization</subject><subject>Oxidation</subject><subject>palladium</subject><subject>Selectivity</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqFkU1vEzEQhi0EoiVw5YgsceGywd_ePUZtSStCGgmqcLOc9WzrsFkHe1dt_j2OEiLEpaeZw_M-mtGL0HtKxpQQ9tl2HsaMUEa0pvoFOqeS0YJrzV_mXXBe6FLSM_QmpXXmy5Ko1-iMcca54OwcrW-fvLO9Dx0ODf4G_YPtAPfhuIYWP_r-AV_vXAz30OEFxJATgO-S7-7x92G7DbEHh6ehdcXCtq11ftjgSduGHZ5nw9bG3tctpLfoVWPbBO-Oc4Tuvlz9uLguZrfTm4vJrKiFELpgSolSK1VbWWlnBXVOgqNWNdA4KRVZrWpLuaKVLlVVS-UU2LKmUlNpGyX4CH06eLcx_B4g9WbjUw35sg7CkAzVhBLJqdDPo0xzWVIl9taP_6HrMMQuP5IpVQlZiSwdofGBqmNIKUJjttFvbNwZSsy-MLMvzJwKy4EPR-2w2oA74X8bykB1AB59C7tndGYyv7n6V14csj718HTK2vjLKM21NMv51PxczuQlWyzNV_4HMRiwsA</recordid><startdate>20130121</startdate><enddate>20130121</enddate><creator>Ab Rahim, Mohd Hasbi</creator><creator>Forde, Michael M.</creator><creator>Jenkins, Robert L.</creator><creator>Hammond, Ceri</creator><creator>He, Qian</creator><creator>Dimitratos, Nikolaos</creator><creator>Lopez-Sanchez, Jose Antonio</creator><creator>Carley, Albert F.</creator><creator>Taylor, Stuart H.</creator><creator>Willock, David J.</creator><creator>Murphy, Damien M.</creator><creator>Kiely, Christopher J.</creator><creator>Hutchings, Graham J.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20130121</creationdate><title>Oxidation of Methane to Methanol with Hydrogen Peroxide Using Supported Gold-Palladium Alloy Nanoparticles</title><author>Ab Rahim, Mohd Hasbi ; Forde, Michael M. ; Jenkins, Robert L. ; Hammond, Ceri ; He, Qian ; Dimitratos, Nikolaos ; Lopez-Sanchez, Jose Antonio ; Carley, Albert F. ; Taylor, Stuart H. ; Willock, David J. ; Murphy, Damien M. ; Kiely, Christopher J. ; Hutchings, Graham J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4447-26648766ca597da41dd5ed1a6fefd5560bbca136197869c56d6ea8c15715af643</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>alloys</topic><topic>Formations</topic><topic>gold</topic><topic>Hydrogen peroxide</topic><topic>Methane</topic><topic>Methyl alcohol</topic><topic>Nanoparticles</topic><topic>Optimization</topic><topic>Oxidation</topic><topic>palladium</topic><topic>Selectivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ab Rahim, Mohd Hasbi</creatorcontrib><creatorcontrib>Forde, Michael M.</creatorcontrib><creatorcontrib>Jenkins, Robert L.</creatorcontrib><creatorcontrib>Hammond, Ceri</creatorcontrib><creatorcontrib>He, Qian</creatorcontrib><creatorcontrib>Dimitratos, Nikolaos</creatorcontrib><creatorcontrib>Lopez-Sanchez, Jose Antonio</creatorcontrib><creatorcontrib>Carley, Albert F.</creatorcontrib><creatorcontrib>Taylor, Stuart H.</creatorcontrib><creatorcontrib>Willock, David J.</creatorcontrib><creatorcontrib>Murphy, Damien M.</creatorcontrib><creatorcontrib>Kiely, Christopher J.</creatorcontrib><creatorcontrib>Hutchings, Graham J.</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ab Rahim, Mohd Hasbi</au><au>Forde, Michael M.</au><au>Jenkins, Robert L.</au><au>Hammond, Ceri</au><au>He, Qian</au><au>Dimitratos, Nikolaos</au><au>Lopez-Sanchez, Jose Antonio</au><au>Carley, Albert F.</au><au>Taylor, Stuart H.</au><au>Willock, David J.</au><au>Murphy, Damien M.</au><au>Kiely, Christopher J.</au><au>Hutchings, Graham J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Oxidation of Methane to Methanol with Hydrogen Peroxide Using Supported Gold-Palladium Alloy Nanoparticles</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. 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subjects | alloys Formations gold Hydrogen peroxide Methane Methyl alcohol Nanoparticles Optimization Oxidation palladium Selectivity |
title | Oxidation of Methane to Methanol with Hydrogen Peroxide Using Supported Gold-Palladium Alloy Nanoparticles |
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