Revisiting zethrene: synthesis, reactivity and semiconductor properties
Zethrene, a unique polycyclic aromatic hydrocarbon with formally fixed C-C double bonds, is predicted to have interesting properties and potential applications as an optical and electronic material. Here we report a novel synthesis of zethrene with improved yield, which presumably involves dinaphtho...
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| Veröffentlicht in: | Chemical science (Cambridge) 2013-07, Vol.4 (8), p.3294-3297 |
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| container_title | Chemical science (Cambridge) |
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| creator | Shan, Liang Liang, Zhixiong Xu, Xiaomin Tang, Qin Miao, Qian |
| description | Zethrene, a unique polycyclic aromatic hydrocarbon with formally fixed C-C double bonds, is predicted to have interesting properties and potential applications as an optical and electronic material. Here we report a novel synthesis of zethrene with improved yield, which presumably involves dinaphtho[10]-annulene as an unstable intermediate. With this convenient access to zethrene, we used zethrene as a p-type semiconductor in thin film transistors for the first time. It is found that Diels-Alder addition to the bay region of zethrene leads to new derivatives of benzo[pqr]naphtho[8,1,2-bcd]peryl ene, which behave as n-type organic semiconductors. |
| doi_str_mv | 10.1039/c3sc51158h |
| format | Article |
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| ispartof | Chemical science (Cambridge), 2013-07, Vol.4 (8), p.3294-3297 |
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| language | eng |
| recordid | cdi_proquest_miscellaneous_1701052118 |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Carbon-carbon composites Derivatives Electronic materials N-type semiconductors Optical properties P-type semiconductors Semiconductors Synthesis |
| title | Revisiting zethrene: synthesis, reactivity and semiconductor properties |
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