A Series of Isoreticular, Highly Stable, Porous Zirconium Oxide Based Metal-Organic Frameworks

Brolly good MOFs: A new series of hydrophobic isoreticular porous Zr oxide dicarboxylate MOFs have been prepared (see picture, Zr blue polyhedra, O red, C black). They have a one‐dimensional pore system, a rare combination of Lewis acidity and hydrophobic character, and a higher hydrothermal and mec...

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Veröffentlicht in:	Angewandte Chemie International Edition 2012-09, Vol.51 (37), p.9267-9271
Hauptverfasser:	Guillerm, V., Ragon, F., Dan-Hardi, M., Devic, T., Vishnuvarthan, M., Campo, B., Vimont, A., Clet, G., Yang, Q., Maurin, G., Férey, G., Vittadini, A., Gross, S., Serre, Christian
Format:	Artikel
Sprache:	eng
Schlagworte:	infrared spectroscopy metal-organic framework Metal-organic frameworks modeling studies Oxides Pictures Polyhedra Polyhedrons Porosity Stability Zirconium Zirconium oxides
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Beschreibung
Zusammenfassung:	Brolly good MOFs: A new series of hydrophobic isoreticular porous Zr oxide dicarboxylate MOFs have been prepared (see picture, Zr blue polyhedra, O red, C black). They have a one‐dimensional pore system, a rare combination of Lewis acidity and hydrophobic character, and a higher hydrothermal and mechanical stability than their UiO MOF polymorph counterparts.
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.201204806