Why Silver Deposition is so Fast: Solving the Enigma of Metal Deposition
A perfect match: Silver deposition is one of the fastest electrochemical reactions, even though the Ag+ ion loses more than 5 eV solvation energy in the process. This phenomenon, an example of the enigma of metal deposition, was investigated by a combination of MD simulations, DFT, and specially dev...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2013-07, Vol.52 (30), p.7883-7885 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Pinto, Leandro M. C. Spohr, Eckhard Quaino, Paola Santos, Elizabeth Schmickler, Wolfgang |
| description | A perfect match: Silver deposition is one of the fastest electrochemical reactions, even though the Ag+ ion loses more than 5 eV solvation energy in the process. This phenomenon, an example of the enigma of metal deposition, was investigated by a combination of MD simulations, DFT, and specially developed theory. At the surface, the Ag+ ion experiences a strong interaction with the sp band of silver, which catalyzes the reaction. |
| doi_str_mv | 10.1002/anie.201301998 |
| format | Article |
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| subjects | corrosion Deposition metal deposition Silver Simulation Solvation theoretical electrochemistry |
| title | Why Silver Deposition is so Fast: Solving the Enigma of Metal Deposition |
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