Synthesis and Complexes of Fluoroalkoxy Carbenes

Gripping ligands: A series of fluoroalkoxy‐functionalized imidazol‐2‐ylidene ligands were synthesized by the alkylation of a range of commercially available azoles with hexafluoroisobutylene oxide. The deprotonation of these species with a strong base cleanly generated the free carbenes, which acted...

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Veröffentlicht in:	Angewandte Chemie International Edition 2013-05, Vol.52 (19), p.5110-5114
Hauptverfasser:	Arduengo III, Anthony J., Dolphin, Joshua S., Gurău, Gabriela, Marshall, William J., Nelson, Joseph C., Petrov, Viacheslav A., Runyon, Jason W.
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkylation Azoles Carbenes Chelating Chelation Cleaning fluorinated ligands Heterocyclic compounds imidazol-2-ylidenes Ligands nitrogen heterocycles Oxides Synthesis tridentate ligands
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