Synthesis, Characterization, and Applications of Zwitterions Containing a Carbanion Moiety
A trifle of triflyl: N‐substituted anilines react with 1,1,3,3‐tetrakis(triflyl)propane to give a 2,2‐bis(triflyl)ethyl group at the para position of the ring. The product is a zwitterion with a carbanion and an ammonium moiety, and can be used as an acid catalyst for organic reactions (see scheme)....
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| Veröffentlicht in: | Angewandte Chemie International Edition 2013-01, Vol.52 (5), p.1560-1563 |
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| container_issue | 5 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Yanai, Hikaru Yoshino, Tasuku Fujita, Masaya Fukaya, Haruhiko Kotani, Akira Kusu, Fumiyo Taguchi, Takeo |
| description | A trifle of triflyl: N‐substituted anilines react with 1,1,3,3‐tetrakis(triflyl)propane to give a 2,2‐bis(triflyl)ethyl group at the para position of the ring. The product is a zwitterion with a carbanion and an ammonium moiety, and can be used as an acid catalyst for organic reactions (see scheme). |
| doi_str_mv | 10.1002/anie.201208809 |
| format | Article |
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| subjects | aldol reaction Aniline Anions - chemistry carbanions Carbon - chemistry Catalysts Crystallography, X-Ray homogeneous catalysis Molecular Conformation Quaternary Ammonium Compounds - chemistry Rings (mathematics) Synthesis synthetic methodology zwitterions |
| title | Synthesis, Characterization, and Applications of Zwitterions Containing a Carbanion Moiety |
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