A few-layered graphene on alumina nanofibers for electrochemical energy conversion
A few-layered graphene on the surface of highly aligned alumina nanofibers (ANFs) with an aspect ratio of 107 was synthesized in a single-step catalyst-free direct chemical vapor deposition process. The product, graphenated alumina nanofibers (G-ANFs), consisting of the ceramic nanofibers surrounded...
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Veröffentlicht in: | Carbon (New York) 2015-07, Vol.88, p.157-164 |
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creator | Hussainova, Irina Ivanov, Roman Stamatin, Serban N. Anoshkin, Ilya V. Skou, Eivind M. Nasibulin, Albert G. |
description | A few-layered graphene on the surface of highly aligned alumina nanofibers (ANFs) with an aspect ratio of 107 was synthesized in a single-step catalyst-free direct chemical vapor deposition process. The product, graphenated alumina nanofibers (G-ANFs), consisting of the ceramic nanofibers surrounded by the conductive and inert few-layered graphene, is a promising material for electrochemical applications. The synthesized material has been demonstrated to be an excellent electrocatalyst support for Pt particles in fuel cells. A 1.5-fold improvement in the mass activity has been obtained for Pt/G-ANF in comparison to the commercially available Pt/C. The electrochemical stability was found to be outstanding for acidic medium electrochemistry. Their remarkable stability and unique structure opens a new avenue for the use of this material in various electrochemical energy conversion technologies. |
doi_str_mv | 10.1016/j.carbon.2015.03.004 |
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The product, graphenated alumina nanofibers (G-ANFs), consisting of the ceramic nanofibers surrounded by the conductive and inert few-layered graphene, is a promising material for electrochemical applications. The synthesized material has been demonstrated to be an excellent electrocatalyst support for Pt particles in fuel cells. A 1.5-fold improvement in the mass activity has been obtained for Pt/G-ANF in comparison to the commercially available Pt/C. The electrochemical stability was found to be outstanding for acidic medium electrochemistry. 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Their remarkable stability and unique structure opens a new avenue for the use of this material in various electrochemical energy conversion technologies.</description><subject>Aluminum oxide</subject><subject>Carbon</subject><subject>Direct power generation</subject><subject>Energy conversion</subject><subject>Graphene</subject><subject>Inert</subject><subject>Nanofibers</subject><subject>Platinum</subject><subject>Stability</subject><issn>0008-6223</issn><issn>1873-3891</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLAzEUhYMoWKv_wEWWbma8ecxrI5TiCwqCdB8ymZs2ZSapSav03ztlXLu6HPjOgfsRcs8gZ8DKx11udGyDzzmwIgeRA8gLMmN1JTJRN-ySzACgzkrOxTW5SWk3RlkzOSOfC2rxJ-v1CSN2dBP1foseafBU98fBeU299sG6FmOiNkSKPZpDDGaLgzO6pyMdNydqgv8eERf8Lbmyuk9493fnZP3yvF6-ZauP1_flYpUZUZWHrKw6aboGGmyYrC2XgGXRaA68gLbR2hrByrIzNaKFojVNUWMFJRctg6qxYk4eptl9DF9HTAc1uGSw77XHcEyKVcBA8prxEZUTamJIKaJV--gGHU-KgTobVDs1GVRngwqEGv2MtaephuMX3w6jSsahN9i5ODpQXXD_D_wCccR8Fw</recordid><startdate>20150701</startdate><enddate>20150701</enddate><creator>Hussainova, Irina</creator><creator>Ivanov, Roman</creator><creator>Stamatin, Serban N.</creator><creator>Anoshkin, Ilya V.</creator><creator>Skou, Eivind M.</creator><creator>Nasibulin, Albert G.</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QQ</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20150701</creationdate><title>A few-layered graphene on alumina nanofibers for electrochemical energy conversion</title><author>Hussainova, Irina ; Ivanov, Roman ; Stamatin, Serban N. ; Anoshkin, Ilya V. ; Skou, Eivind M. ; Nasibulin, Albert G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c376t-67d4cd909e9148f240e659a20250b9aafc3166dc8eef05bc958e70623b1079f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Aluminum oxide</topic><topic>Carbon</topic><topic>Direct power generation</topic><topic>Energy conversion</topic><topic>Graphene</topic><topic>Inert</topic><topic>Nanofibers</topic><topic>Platinum</topic><topic>Stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hussainova, Irina</creatorcontrib><creatorcontrib>Ivanov, Roman</creatorcontrib><creatorcontrib>Stamatin, Serban N.</creatorcontrib><creatorcontrib>Anoshkin, Ilya V.</creatorcontrib><creatorcontrib>Skou, Eivind M.</creatorcontrib><creatorcontrib>Nasibulin, Albert G.</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Carbon (New York)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hussainova, Irina</au><au>Ivanov, Roman</au><au>Stamatin, Serban N.</au><au>Anoshkin, Ilya V.</au><au>Skou, Eivind M.</au><au>Nasibulin, Albert G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A few-layered graphene on alumina nanofibers for electrochemical energy conversion</atitle><jtitle>Carbon (New York)</jtitle><date>2015-07-01</date><risdate>2015</risdate><volume>88</volume><spage>157</spage><epage>164</epage><pages>157-164</pages><issn>0008-6223</issn><eissn>1873-3891</eissn><abstract>A few-layered graphene on the surface of highly aligned alumina nanofibers (ANFs) with an aspect ratio of 107 was synthesized in a single-step catalyst-free direct chemical vapor deposition process. 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subjects | Aluminum oxide Carbon Direct power generation Energy conversion Graphene Inert Nanofibers Platinum Stability |
title | A few-layered graphene on alumina nanofibers for electrochemical energy conversion |
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