Mechanistic Insights into Thermal Stability Improvement of exo-Tetrahydrodicyclopentadiene by a New Hydrogen Donor: 5,6,7,8-Tetrafluoro-1,2,3,4-tetrahydroquinoxaline

Mechanistic Insights into Thermal Stability Improvement of exo-Tetrahydrodicyclopentadiene by a New Hydrogen Donor: 5,6,7,8-Tetrafluoro-1,2,3,4-tetrahydroquinoxaline

We investigated the thermal stability of exo-tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of 5,6,7,8-tetrafluoro-1,2,3,4-tetrahydroquinoxaline (TFQox), a new hydrogen donor (H donor). Conversion of exo-THDCP was slowed in the presence of TFQox but less effectively comp...

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Veröffentlicht in:Energy & fuels 2015-01, Vol.29 (1), p.16-20
Hauptverfasser: Park, Sun Hee, Park, Yumi, Han, Jeong Sik, Jeong, Byung Hun, Han, Hogyu, Kim, Sung Hyun
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Conversion
Fuels
Thermal decomposition
Thermal stability
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container_issue 1
container_start_page 16
container_title Energy & fuels
container_volume 29
creator Park, Sun Hee
Park, Yumi
Han, Jeong Sik
Jeong, Byung Hun
Han, Hogyu
Kim, Sung Hyun
description We investigated the thermal stability of exo-tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of 5,6,7,8-tetrafluoro-1,2,3,4-tetrahydroquinoxaline (TFQox), a new hydrogen donor (H donor). Conversion of exo-THDCP was slowed in the presence of TFQox but less effectively compared to its analogues, 1,2,3,4-tetrahydroquinoxaline (THQox) and 1,2,3,4-tetrahydroquinoline (THQ). We analyzed the H-donor effects on the thermal decomposition kinetics of exo-THDCP, which explains the relative effect of the H donors on the thermal stability improvement of exo-THDCP.
doi_str_mv 10.1021/ef5016445
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subjects Conversion
Fuels
Thermal decomposition
Thermal stability
title Mechanistic Insights into Thermal Stability Improvement of exo-Tetrahydrodicyclopentadiene by a New Hydrogen Donor: 5,6,7,8-Tetrafluoro-1,2,3,4-tetrahydroquinoxaline
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