Cationic Gold(III) Alkyl Complexes: Generation, Trapping, and Insertion of Norbornene

Migratory insertion of alkenes into gold–carbon bonds, a fundamental yet unprecedented organometallic transformation, has been investigated from a discrete (P,C) cyclometalated gold(III) dimethyl complex. Methide ion by B(C6F5)3 is shown to generate a highly reactive cationic AuIII complex that evol...

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Veröffentlicht in:	Angewandte Chemie International Edition 2015-01, Vol.54 (4), p.1266-1269
Hauptverfasser:	Rekhroukh, Feriel, Brousses, Rémy, Amgoune, Abderrahmane, Bourissou, Didier
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Cationic Chlorides Dimethyl gold Insertion insertion reactions Lewis acids Metalorganic compounds olefins organometallic chemistry Pyridines Transformations Trapping
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