Neutron Diffraction Analysis of a Single-Crystal Structure of Rb sub( 0.51)Tl sub( 0.49)H sub( 2)PO sub( 4)

A crystal structure analysis of the mixed crystal ... was conducted at ambient temperature by neutron diffraction analysis using a high-quality single crystal grown from an aqueous solution. ... and ... (TDP) exhibit clearly different crystal structures from each other, although Rb + and Tl + have a...

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Veröffentlicht in:Journal of the Physical Society of Japan 2011-08, Vol.80 (8), p.1-1
Hauptverfasser: Oh, In-Hwan, Meven, Martin, Heger, Gernot, Lee, Kwang-Sei
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container_title Journal of the Physical Society of Japan
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creator Oh, In-Hwan
Meven, Martin
Heger, Gernot
Lee, Kwang-Sei
description A crystal structure analysis of the mixed crystal ... was conducted at ambient temperature by neutron diffraction analysis using a high-quality single crystal grown from an aqueous solution. ... and ... (TDP) exhibit clearly different crystal structures from each other, although Rb + and Tl + have almost the same ionic radii. The crystal structure of the title compound, i.e., ..., is isotypic to ..., having partially disordered H atoms in strong symmetry hydrogen bonds. The lone-pair electrons of Tl + ions are considered to have an effect on the stabilization of the two-dimensional network of hydrogen-bonded ... groups. Although the difference in chemical composition is very subtle, in contrast to the previous case of ..., the distribution of the lone-pair electrons seems to change and the hydrogen bond angle, especially for disordered hydrogen atoms, also shows significant changes. (ProQuest: ... denotes formulae/symbols omitted.)
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subjects Ambient temperature
Atomic structure
Crystal structure
Hydrogen atoms
Hydrogen bonds
Mixed crystals
Neutron diffraction
Single crystals
Stabilization
title Neutron Diffraction Analysis of a Single-Crystal Structure of Rb sub( 0.51)Tl sub( 0.49)H sub( 2)PO sub( 4)
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