Introducing Deep Eutectic Solvents to Polar Organometallic Chemistry: Chemoselective Addition of Organolithium and Grignard Reagents to Ketones in Air

Despite their enormous synthetic relevance, the use of polar organolithium and Grignard reagents is greatly limited by their requirements of low temperatures in order to control their reactivity as well as the need of dry organic solvents and inert atmosphere protocols to avoid their fast decomposit...

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Veröffentlicht in:	Angewandte Chemie International Edition 2014-06, Vol.53 (23), p.5969-5973
Hauptverfasser:	Vidal, Cristian, García-Álvarez, Joaquín, Hernán-Gómez, Alberto, Kennedy, Alan R., Hevia, Eva
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation addition reactions Chlorides deep eutectic solvents Eutectics green chemistry Grignard reagents Ketones Lithium Media Metalorganic compounds organolithium compounds Organometallic compounds Solvents
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