A Two-in-one Pincer Ligand and its Diiron(II) Complex Showing Spin State Switching in Solution through Reversible Ligand Exchange

A novel pyrazolate‐bridged ligand providing two {PNN} pincer‐type compartments has been synthesized. Its diiron(II) complex LFe2(OTf)3(CH3CN) (1; Tf=triflate) features, in solid state, two bridging triflate ligands, with a terminal triflate and a MeCN ligand completing the octahedral coordination sp...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Angewandte Chemie International Edition 2015-01, Vol.54 (2), p.583-587
Hauptverfasser:	Samanta, Subhas, Demesko, Serhiy, Dechert, Sebastian, Meyer, Franc
Format:	Artikel
Sprache:	eng
Schlagworte:	Compartments Correlation diiron complexes Exchange Ion exchangers ligand exchange Ligands magnetic properties pincer ligands Spectrum analysis spin crossover Spin transition Switching Terminals
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!