Asymmetric Hydrogenation of Maleic Acid Diesters and Anhydrides

Asymmetric hydrogenation of maleic and fumaric acid derivatives with iridium catalysts based on N,P ligands provides an efficient route to chiral enantioenriched succinates. A new catalyst derived from a 2,6‐difluorophenyl‐substituted pyridine‐phosphinite ligand was developed and enables the convers...

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Veröffentlicht in:	Angewandte Chemie International Edition 2014-05, Vol.53 (21), p.5385-5388
Hauptverfasser:	Bernasconi, Maurizio, Müller, Marc-André, Pfaltz, Andreas
Format:	Artikel
Sprache:	eng
Schlagworte:	asymmetric catalysis Asymmetry Biocompatibility Catalysis Catalysts Derivatives Fumaric acid Hydrogenation Inhibitors iridium Ligands N,P ligands P ligands synthetic methods
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