Stereospecific Formal [3+2] Dipolar Cycloaddition of Cyclopropanes with Nitrosoarenes: An Approach to Isoxazolidines

The MgBr2‐catalyzed formal [3+2] cycloaddition of donor–acceptor activated cyclopropanes with nitrosoarenes offers a novel approach to various structurally diverse isoxazolidines. The reactions, which are experimentally easy to conduct, occur with complete stereospecificity and perfect control of re...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Angewandte Chemie International Edition 2014-06, Vol.53 (23), p.5964-5968
Hauptverfasser:	Chakrabarty, Shyamal, Chatterjee, Indranil, Wibbeling, Birgit, Daniliuc, Constantin Gabriel, Studer, Armido
Format:	Artikel
Sprache:	eng
Schlagworte:	Activated Bonding Borides Cleavage Cycloaddition cycloadditions cyclopropanes heterocycles Isoxazolidines Lactones Magnesium compounds nitrosoarene Organic compounds stereoselective synthesis
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!