An Efficient Nanoscale Heterogeneous Catalyst for the Capture and Conversion of Carbon Dioxide at Ambient Pressure
Silver nanoparticles were successfully supported on the zeolite‐type metal–organic framework MIL‐101 to yield Ag@MIL‐101 by a simple liquid impregnation method. For the first time, the conversion of terminal alkynes into propiolic acids with CO2 was achieved by the use of the Ag@MIL‐101 catalysts. O...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2015-01, Vol.54 (3), p.988-991 |
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| creator | Liu, Xiao-Huan Ma, Jian-Gong Niu, Zheng Yang, Guang-Ming Cheng, Peng |
| description | Silver nanoparticles were successfully supported on the zeolite‐type metal–organic framework MIL‐101 to yield Ag@MIL‐101 by a simple liquid impregnation method. For the first time, the conversion of terminal alkynes into propiolic acids with CO2 was achieved by the use of the Ag@MIL‐101 catalysts. Owing to the excellent catalytic activity, the reaction proceeded at atmospheric pressure and low temperature (50 °C). The Ag@MIL‐101 porous material is of outstanding bifunctional character as it is capable of simultaneously capturing and converting CO2 with low energy consumption and can be recovered easily by centrifugation.
Silver nanoparticles were supported on the zeolite‐type metal–organic framework MIL‐101 by a simple liquid impregnation method to yield Ag@MIL‐101. CO2 and terminal alkynes could be converted into propiolic acids in the presence of the very active Ag@MIL‐101 catalyst at atmospheric pressure and low temperature (50 °C). |
| doi_str_mv | 10.1002/anie.201409103 |
| format | Article |
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Silver nanoparticles were supported on the zeolite‐type metal–organic framework MIL‐101 by a simple liquid impregnation method to yield Ag@MIL‐101. CO2 and terminal alkynes could be converted into propiolic acids in the presence of the very active Ag@MIL‐101 catalyst at atmospheric pressure and low temperature (50 °C).</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201409103</identifier><identifier>PMID: 25385217</identifier><identifier>CODEN: ACIEAY</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Alkynes ; Atmospheric pressure ; Barometric pressure ; Carbon dioxide ; carbon dioxide fixation ; Catalysts ; heterogeneous catalysis ; Liquids ; metal-organic frameworks ; propiolic acids ; Silver ; silver nanoparticles ; Terminals</subject><ispartof>Angewandte Chemie International Edition, 2015-01, Vol.54 (3), p.988-991</ispartof><rights>2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5473-35b00e3416f3363f26a69ecaa6a29117c98eabb2a264423bdc5f964722009eaf3</citedby><cites>FETCH-LOGICAL-c5473-35b00e3416f3363f26a69ecaa6a29117c98eabb2a264423bdc5f964722009eaf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201409103$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201409103$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25385217$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Liu, Xiao-Huan</creatorcontrib><creatorcontrib>Ma, Jian-Gong</creatorcontrib><creatorcontrib>Niu, Zheng</creatorcontrib><creatorcontrib>Yang, Guang-Ming</creatorcontrib><creatorcontrib>Cheng, Peng</creatorcontrib><title>An Efficient Nanoscale Heterogeneous Catalyst for the Capture and Conversion of Carbon Dioxide at Ambient Pressure</title><title>Angewandte Chemie International Edition</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>Silver nanoparticles were successfully supported on the zeolite‐type metal–organic framework MIL‐101 to yield Ag@MIL‐101 by a simple liquid impregnation method. For the first time, the conversion of terminal alkynes into propiolic acids with CO2 was achieved by the use of the Ag@MIL‐101 catalysts. Owing to the excellent catalytic activity, the reaction proceeded at atmospheric pressure and low temperature (50 °C). The Ag@MIL‐101 porous material is of outstanding bifunctional character as it is capable of simultaneously capturing and converting CO2 with low energy consumption and can be recovered easily by centrifugation.
Silver nanoparticles were supported on the zeolite‐type metal–organic framework MIL‐101 by a simple liquid impregnation method to yield Ag@MIL‐101. CO2 and terminal alkynes could be converted into propiolic acids in the presence of the very active Ag@MIL‐101 catalyst at atmospheric pressure and low temperature (50 °C).</description><subject>Alkynes</subject><subject>Atmospheric pressure</subject><subject>Barometric pressure</subject><subject>Carbon dioxide</subject><subject>carbon dioxide fixation</subject><subject>Catalysts</subject><subject>heterogeneous catalysis</subject><subject>Liquids</subject><subject>metal-organic frameworks</subject><subject>propiolic acids</subject><subject>Silver</subject><subject>silver nanoparticles</subject><subject>Terminals</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqFkcFv0zAUhy0EYmPjyhFZ4sIlxfZz7ORYdV03aSpo2gbiYjnpM3ikcbETWP97vHVUiMvkg5_s7_dJTz9C3nA24YyJD7b3OBGMS1ZzBs_IIS8FL0BreJ5nCVDoquQH5FVKt5mvKqZekgNRQpU5fUjitKdz53zrsR_o0vYhtbZDeoYDxvANewxjojM72G6bBupCpMN3zA-bYYxIbb-is9D_wph86Glw-Sc2eTrx4c6vMjDQ6bp5kH-KmFIOHZMXznYJXz_eR-T6dH41OysuPi7OZ9OLoi2lhgLKhjEEyZUDUOCEsqrG1lplRc25busKbdMIK5SUAppVW7paSS0EYzVaB0fk_c67ieHniGkwa59a7Dr7sJThmvF8JJNPo6oUoBXUOqPv_kNvwxj7vEimJHDIoMjUZEe1MaQU0ZlN9Gsbt4Yzc1-cuS_O7IvLgbeP2rFZ42qP_20qA_UO-O073D6hM9Pl-fxfebHL-jTg3T5r4w-jNOjSfF4uzJW-uYQvXxfmFP4AMyiysw</recordid><startdate>20150112</startdate><enddate>20150112</enddate><creator>Liu, Xiao-Huan</creator><creator>Ma, Jian-Gong</creator><creator>Niu, Zheng</creator><creator>Yang, Guang-Ming</creator><creator>Cheng, Peng</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>KR7</scope></search><sort><creationdate>20150112</creationdate><title>An Efficient Nanoscale Heterogeneous Catalyst for the Capture and Conversion of Carbon Dioxide at Ambient Pressure</title><author>Liu, Xiao-Huan ; Ma, Jian-Gong ; Niu, Zheng ; Yang, Guang-Ming ; Cheng, Peng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5473-35b00e3416f3363f26a69ecaa6a29117c98eabb2a264423bdc5f964722009eaf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Alkynes</topic><topic>Atmospheric pressure</topic><topic>Barometric pressure</topic><topic>Carbon dioxide</topic><topic>carbon dioxide fixation</topic><topic>Catalysts</topic><topic>heterogeneous catalysis</topic><topic>Liquids</topic><topic>metal-organic frameworks</topic><topic>propiolic acids</topic><topic>Silver</topic><topic>silver nanoparticles</topic><topic>Terminals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Xiao-Huan</creatorcontrib><creatorcontrib>Ma, Jian-Gong</creatorcontrib><creatorcontrib>Niu, Zheng</creatorcontrib><creatorcontrib>Yang, Guang-Ming</creatorcontrib><creatorcontrib>Cheng, Peng</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Civil Engineering Abstracts</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Xiao-Huan</au><au>Ma, Jian-Gong</au><au>Niu, Zheng</au><au>Yang, Guang-Ming</au><au>Cheng, Peng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An Efficient Nanoscale Heterogeneous Catalyst for the Capture and Conversion of Carbon Dioxide at Ambient Pressure</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. Chem. Int. Ed</addtitle><date>2015-01-12</date><risdate>2015</risdate><volume>54</volume><issue>3</issue><spage>988</spage><epage>991</epage><pages>988-991</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><coden>ACIEAY</coden><abstract>Silver nanoparticles were successfully supported on the zeolite‐type metal–organic framework MIL‐101 to yield Ag@MIL‐101 by a simple liquid impregnation method. For the first time, the conversion of terminal alkynes into propiolic acids with CO2 was achieved by the use of the Ag@MIL‐101 catalysts. Owing to the excellent catalytic activity, the reaction proceeded at atmospheric pressure and low temperature (50 °C). The Ag@MIL‐101 porous material is of outstanding bifunctional character as it is capable of simultaneously capturing and converting CO2 with low energy consumption and can be recovered easily by centrifugation.
Silver nanoparticles were supported on the zeolite‐type metal–organic framework MIL‐101 by a simple liquid impregnation method to yield Ag@MIL‐101. CO2 and terminal alkynes could be converted into propiolic acids in the presence of the very active Ag@MIL‐101 catalyst at atmospheric pressure and low temperature (50 °C).</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>25385217</pmid><doi>10.1002/anie.201409103</doi><tpages>4</tpages><edition>International ed. in English</edition></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Alkynes Atmospheric pressure Barometric pressure Carbon dioxide carbon dioxide fixation Catalysts heterogeneous catalysis Liquids metal-organic frameworks propiolic acids Silver silver nanoparticles Terminals |
| title | An Efficient Nanoscale Heterogeneous Catalyst for the Capture and Conversion of Carbon Dioxide at Ambient Pressure |
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