Supramolecular [60]Fullerene Liquid Crystals Formed By Self-Organized Two-Dimensional Crystals
Fullerene‐based liquid crystalline materials have both the excellent optical and electrical properties of fullerene and the self‐organization and external‐field‐responsive properties of liquid crystals (LCs). Herein, we demonstrate a new family of thermotropic [60]fullerene supramolecular LCs with h...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2015-01, Vol.54 (1), p.114-117 |
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| creator | Zhang, Xiaoyan Hsu, Chih-Hao Ren, Xiangkui Gu, Yan Song, Bo Sun, Hao-Jan Yang, Shuang Chen, Erqiang Tu, Yingfeng Li, Xiaohong Yang, Xiaoming Li, Yaowen Zhu, Xiulin |
| description | Fullerene‐based liquid crystalline materials have both the excellent optical and electrical properties of fullerene and the self‐organization and external‐field‐responsive properties of liquid crystals (LCs). Herein, we demonstrate a new family of thermotropic [60]fullerene supramolecular LCs with hierarchical structures. The [60]fullerene dyads undergo self‐organization driven by π–π interactions to form triple‐layer two‐dimensional (2D) fullerene crystals sandwiched between layers of alkyl chains. The lamellar packing of 2D crystals gives rise to the formation of supramolecular LCs. This design strategy should be applicable to other molecules and lead to an enlarged family of 2D crystals and supramolecular liquid crystals.
Soft materials: A series of fullerene dyads self‐organize to form two‐dimensional crystals through π–π interactions between fullerenes. Lamellar packing of the 2D crystals gives rise to the formation of a new family of thermotropic supramolecular liquid crystals with hierarchical structures. |
| doi_str_mv | 10.1002/anie.201408438 |
| format | Article |
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Soft materials: A series of fullerene dyads self‐organize to form two‐dimensional crystals through π–π interactions between fullerenes. Lamellar packing of the 2D crystals gives rise to the formation of a new family of thermotropic supramolecular liquid crystals with hierarchical structures.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201408438</identifier><identifier>PMID: 25327867</identifier><identifier>CODEN: ACIEAY</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Crystals ; Electrical properties ; Formations ; Fullerenes ; Lamellar structure ; Liquid crystals ; Optical properties ; self-assembly ; Strategy ; Structural hierarchy ; Two dimensional ; X-ray diffraction ; π interactions</subject><ispartof>Angewandte Chemie International Edition, 2015-01, Vol.54 (1), p.114-117</ispartof><rights>2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright Wiley Subscription Services, Inc. Jan 2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5758-c05aeb372b7291a5c6af94bdc627baa7a476726525890a5c6ddc76fc0ee007cf3</citedby><cites>FETCH-LOGICAL-c5758-c05aeb372b7291a5c6af94bdc627baa7a476726525890a5c6ddc76fc0ee007cf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201408438$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201408438$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25327867$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Xiaoyan</creatorcontrib><creatorcontrib>Hsu, Chih-Hao</creatorcontrib><creatorcontrib>Ren, Xiangkui</creatorcontrib><creatorcontrib>Gu, Yan</creatorcontrib><creatorcontrib>Song, Bo</creatorcontrib><creatorcontrib>Sun, Hao-Jan</creatorcontrib><creatorcontrib>Yang, Shuang</creatorcontrib><creatorcontrib>Chen, Erqiang</creatorcontrib><creatorcontrib>Tu, Yingfeng</creatorcontrib><creatorcontrib>Li, Xiaohong</creatorcontrib><creatorcontrib>Yang, Xiaoming</creatorcontrib><creatorcontrib>Li, Yaowen</creatorcontrib><creatorcontrib>Zhu, Xiulin</creatorcontrib><title>Supramolecular [60]Fullerene Liquid Crystals Formed By Self-Organized Two-Dimensional Crystals</title><title>Angewandte Chemie International Edition</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>Fullerene‐based liquid crystalline materials have both the excellent optical and electrical properties of fullerene and the self‐organization and external‐field‐responsive properties of liquid crystals (LCs). Herein, we demonstrate a new family of thermotropic [60]fullerene supramolecular LCs with hierarchical structures. The [60]fullerene dyads undergo self‐organization driven by π–π interactions to form triple‐layer two‐dimensional (2D) fullerene crystals sandwiched between layers of alkyl chains. The lamellar packing of 2D crystals gives rise to the formation of supramolecular LCs. This design strategy should be applicable to other molecules and lead to an enlarged family of 2D crystals and supramolecular liquid crystals.
Soft materials: A series of fullerene dyads self‐organize to form two‐dimensional crystals through π–π interactions between fullerenes. Lamellar packing of the 2D crystals gives rise to the formation of a new family of thermotropic supramolecular liquid crystals with hierarchical structures.</description><subject>Crystals</subject><subject>Electrical properties</subject><subject>Formations</subject><subject>Fullerenes</subject><subject>Lamellar structure</subject><subject>Liquid crystals</subject><subject>Optical properties</subject><subject>self-assembly</subject><subject>Strategy</subject><subject>Structural hierarchy</subject><subject>Two dimensional</subject><subject>X-ray diffraction</subject><subject>π interactions</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqFkUtv1DAUha0K1BdsWaJIbNhk8CN-ZNkOnT40tIgWIYHAcpwb5NZJpvZEZfj19ShlVHVBV9eyv3Nsn4PQG4InBGP6wXQOJhSTAquCqS20SzglOZOSvUjrgrFcKk520F6M14lXCotttEM5o1IJuYt-XQ6LYNregx28CdkPgX_OBu8hQAfZ3N0Ors6mYRWXxsds1ocW6uxwlV2Cb_KL8Dvd_zftXN31-UfXQhdd3xm_UbxCL5s04PXD3EdfZ0dX05N8fnF8Oj2Y55ZLrnKLuYGKSVpJWhLDrTBNWVS1FVRWxkhTSCGp4JSrEq-P69pK0VgMgLG0DdtH70ffRehvB4hL3bpowXvTQT9ETSROceGSFc-joqCCpLeohL57gl73Q0j_i5pyIUhKk_2XSl5YCTJSk5GyoY8xQKMXwbUmrDTBel2lXlepN1UmwdsH26FKoW_wf90loByBO-dh9YydPjg_PXpsno9aF5fwZ6M14UYnZ8n1t_Nj_fnL4fdPqij1GbsHy_q4Pg</recordid><startdate>20150102</startdate><enddate>20150102</enddate><creator>Zhang, Xiaoyan</creator><creator>Hsu, Chih-Hao</creator><creator>Ren, Xiangkui</creator><creator>Gu, Yan</creator><creator>Song, Bo</creator><creator>Sun, Hao-Jan</creator><creator>Yang, Shuang</creator><creator>Chen, Erqiang</creator><creator>Tu, Yingfeng</creator><creator>Li, Xiaohong</creator><creator>Yang, Xiaoming</creator><creator>Li, Yaowen</creator><creator>Zhu, Xiulin</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20150102</creationdate><title>Supramolecular [60]Fullerene Liquid Crystals Formed By Self-Organized Two-Dimensional Crystals</title><author>Zhang, Xiaoyan ; Hsu, Chih-Hao ; Ren, Xiangkui ; Gu, Yan ; Song, Bo ; Sun, Hao-Jan ; Yang, Shuang ; Chen, Erqiang ; Tu, Yingfeng ; Li, Xiaohong ; Yang, Xiaoming ; Li, Yaowen ; Zhu, Xiulin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5758-c05aeb372b7291a5c6af94bdc627baa7a476726525890a5c6ddc76fc0ee007cf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Crystals</topic><topic>Electrical properties</topic><topic>Formations</topic><topic>Fullerenes</topic><topic>Lamellar structure</topic><topic>Liquid crystals</topic><topic>Optical properties</topic><topic>self-assembly</topic><topic>Strategy</topic><topic>Structural hierarchy</topic><topic>Two dimensional</topic><topic>X-ray diffraction</topic><topic>π interactions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Xiaoyan</creatorcontrib><creatorcontrib>Hsu, Chih-Hao</creatorcontrib><creatorcontrib>Ren, Xiangkui</creatorcontrib><creatorcontrib>Gu, Yan</creatorcontrib><creatorcontrib>Song, Bo</creatorcontrib><creatorcontrib>Sun, Hao-Jan</creatorcontrib><creatorcontrib>Yang, Shuang</creatorcontrib><creatorcontrib>Chen, Erqiang</creatorcontrib><creatorcontrib>Tu, Yingfeng</creatorcontrib><creatorcontrib>Li, Xiaohong</creatorcontrib><creatorcontrib>Yang, Xiaoming</creatorcontrib><creatorcontrib>Li, Yaowen</creatorcontrib><creatorcontrib>Zhu, Xiulin</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Xiaoyan</au><au>Hsu, Chih-Hao</au><au>Ren, Xiangkui</au><au>Gu, Yan</au><au>Song, Bo</au><au>Sun, Hao-Jan</au><au>Yang, Shuang</au><au>Chen, Erqiang</au><au>Tu, Yingfeng</au><au>Li, Xiaohong</au><au>Yang, Xiaoming</au><au>Li, Yaowen</au><au>Zhu, Xiulin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Supramolecular [60]Fullerene Liquid Crystals Formed By Self-Organized Two-Dimensional Crystals</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. 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Soft materials: A series of fullerene dyads self‐organize to form two‐dimensional crystals through π–π interactions between fullerenes. Lamellar packing of the 2D crystals gives rise to the formation of a new family of thermotropic supramolecular liquid crystals with hierarchical structures.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>25327867</pmid><doi>10.1002/anie.201408438</doi><tpages>4</tpages><edition>International ed. in English</edition></addata></record> |
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| subjects | Crystals Electrical properties Formations Fullerenes Lamellar structure Liquid crystals Optical properties self-assembly Strategy Structural hierarchy Two dimensional X-ray diffraction π interactions |
| title | Supramolecular [60]Fullerene Liquid Crystals Formed By Self-Organized Two-Dimensional Crystals |
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