How Absorbed Hydrogen Affects the Catalytic Activity of Transition Metals

Heterogeneous catalysis is commonly governed by surface active sites. Yet, areas just below the surface can also influence catalytic activity, for instance, when fragmentation products of catalytic feeds penetrate into catalysts. In particular, H absorbed below the surface is required for certain hy...

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Veröffentlicht in:	Angewandte Chemie International Edition 2014-12, Vol.53 (49), p.13371-13375
Hauptverfasser:	Aleksandrov, Hristiyan A., Kozlov, Sergey M., Schauermann, Swetlana, Vayssilov, Georgi N., Neyman, Konstantin M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Adsorption Catalysis Catalytic activity density functional calculations heterogeneous catalysis Hydrogen - chemistry Hydrogen storage Hydrogenation hydrogenations Metal Nanoparticles - chemistry Metals Metals - chemistry Models, Molecular Nanoparticles Nickel Palladium Platinum Surface chemistry Surface Properties Transition Elements - chemistry Transition metals
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