Direct Benzylic CH Activation for CO Bond Formation by Photoredox Catalysis
Power of light: 1,4‐dicyanonaphthalene (DCN) and light directly activates benzylic CH bonds for intra‐ and intermolecular CO bond formation. Arylalkyls have also been transformed directly into aryl ketones using water as a source of oxygen. EDG=electron‐donating group, EWG=electron‐withdrawing gro...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2013-05, Vol.52 (19), p.5146-5149 |
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| container_issue | 19 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Pandey, Ganesh Pal, Sujit Laha, Ramkrishna |
| description | Power of light: 1,4‐dicyanonaphthalene (DCN) and light directly activates benzylic CH bonds for intra‐ and intermolecular CO bond formation. Arylalkyls have also been transformed directly into aryl ketones using water as a source of oxygen. EDG=electron‐donating group, EWG=electron‐withdrawing group. |
| doi_str_mv | 10.1002/anie.201210333 |
| format | Article |
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| ispartof | Angewandte Chemie International Edition, 2013-05, Vol.52 (19), p.5146-5149 |
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| language | eng |
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| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | Activation arenes Aromatic compounds Benzene Derivatives - chemistry Bonding Catalysis CH activation heterocycles Ketones Ketones - chemistry Light Molecular Structure Naphthalenes - chemistry Oxidation-Reduction Oxygen - chemistry photochemistry Photoredox catalysis reaction mechanisms |
| title | Direct Benzylic CH Activation for CO Bond Formation by Photoredox Catalysis |
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