Highly Linear Selective Cobalt-Catalyzed Addition of Aryl Imines to Styrenes: Reversing Intrinsic Regioselectivity by Ligand Elaboration

Highly linear selective, imine‐directed hydroarylation of styrene has been achieved with cobalt‐based catalytic systems featuring bis(2,4‐dimethoxyphenyl)(phenyl)phosphine and either 2‐methoxypyridine or DBU as a ligand and a Lewis base additive, respectively, thus affording a variety of 1,2‐diaryle...

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Veröffentlicht in:	Angewandte Chemie International Edition 2014-12, Vol.53 (51), p.14166-14170
Hauptverfasser:	Xu, Wengang, Yoshikai, Naohiko
Format:	Artikel
Sprache:	eng
Schlagworte:	alkenes Aromatic compounds Catalysis Catalysts cobalt CH activation Imines Lewis base Ligands regioselectivity Reversing Screening Styrenes synthetic methods
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