Supramolecular Assembly through Interactions between Molecular Dipoles and Alkali Metal Ions
Establishing a way to fabricate well‐ordered molecular structures is a necessary step toward advancement in organic optoelectronic devices. Here, we propose to use interactions between electric dipoles of molecules and alkali metal ions to form a well‐developed homogeneous monolayer of diarylethene...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2014-12, Vol.53 (50), p.13729-13733 |
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| creator | Shimizu, Tomoko K. Jung, Jaehoon Imada, Hiroshi Kim, Yousoo |
| description | Establishing a way to fabricate well‐ordered molecular structures is a necessary step toward advancement in organic optoelectronic devices. Here, we propose to use interactions between electric dipoles of molecules and alkali metal ions to form a well‐developed homogeneous monolayer of diarylethene molecules on the Cu(111) surface with the aid of NaCl co‐deposition. Scanning tunneling microscopy and density functional theory calculation results indicate that the formation of a row‐type structure occurs as a result of interactions between the Na+ ions and the diarylethene molecular dipoles, drastically changing the adsorption configuration from that without Na+.
Only with Na+: Diarylethene molecules are arranged into a well‐ordered film on Cu(111) through supramolecular assembly with the aid of NaCl co‐deposition. Interactions between molecular dipoles and Na+ cations are the driving force for the superstructure formation. |
| doi_str_mv | 10.1002/anie.201407555 |
| format | Article |
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Only with Na+: Diarylethene molecules are arranged into a well‐ordered film on Cu(111) through supramolecular assembly with the aid of NaCl co‐deposition. Interactions between molecular dipoles and Na+ cations are the driving force for the superstructure formation.</description><subject>Alkali metals</subject><subject>Assembly</subject><subject>density functional calculations</subject><subject>Density functional theory</subject><subject>diarylethene</subject><subject>Dipoles</subject><subject>Electric dipoles</subject><subject>Formations</subject><subject>Molecular structure</subject><subject>scanning probe microscopy</subject><subject>Superstructures</subject><subject>supramolecular chemistry</subject><subject>Surface chemistry</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqF0U1v1DAQBuAIgWhpuXJElrhwyeLP2D6u2rJdqS2IfiAhJGuSTGhaJ1nsRO3-e7zaskJcevHM4ZlXst4se8fojFHKP0Hf4oxTJqlWSr3I9pniLBdai5dpl0Lk2ii2l72J8S55Y2jxOtvjSijBGN3Pfl5OqwDd4LGaPAQyjxG70q_JeBuG6dctWfYjBqjGdugjKXF8QOzJ-c4ft6u0RwJ9Teb-HnxLznEET5bJH2avGvAR3z7Ng-z688nV0Wl-9mWxPJqf5ZUyWuVQUM5KqppCCKlLsFTyQpgGKLdApbQNAlrOeVXVrJZNDWVZUqEYMFmBsOIg-7jNXYXh94RxdF0bK_Qeehym6Jim1BqT3udpISTXjIsN_fAfvRum0KePJMWtFFIVJqnZVlVhiDFg41ah7SCsHaNuU5HbVOR2FaWD90-xU9lhveN_O0nAbsFD63H9TJybXyxP_g3Pt7dtHPFxdwvh3hVaaOW-Xyzcj6_amm83N24h_gCJu6vA</recordid><startdate>20141208</startdate><enddate>20141208</enddate><creator>Shimizu, Tomoko K.</creator><creator>Jung, Jaehoon</creator><creator>Imada, Hiroshi</creator><creator>Kim, Yousoo</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20141208</creationdate><title>Supramolecular Assembly through Interactions between Molecular Dipoles and Alkali Metal Ions</title><author>Shimizu, Tomoko K. ; Jung, Jaehoon ; Imada, Hiroshi ; Kim, Yousoo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5875-a6021b05f63347ba9042638fa029a0449feae9222ccd1d4fdabbb0351a14ca393</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Alkali metals</topic><topic>Assembly</topic><topic>density functional calculations</topic><topic>Density functional theory</topic><topic>diarylethene</topic><topic>Dipoles</topic><topic>Electric dipoles</topic><topic>Formations</topic><topic>Molecular structure</topic><topic>scanning probe microscopy</topic><topic>Superstructures</topic><topic>supramolecular chemistry</topic><topic>Surface chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shimizu, Tomoko K.</creatorcontrib><creatorcontrib>Jung, Jaehoon</creatorcontrib><creatorcontrib>Imada, Hiroshi</creatorcontrib><creatorcontrib>Kim, Yousoo</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shimizu, Tomoko K.</au><au>Jung, Jaehoon</au><au>Imada, Hiroshi</au><au>Kim, Yousoo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Supramolecular Assembly through Interactions between Molecular Dipoles and Alkali Metal Ions</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. 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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Alkali metals Assembly density functional calculations Density functional theory diarylethene Dipoles Electric dipoles Formations Molecular structure scanning probe microscopy Superstructures supramolecular chemistry Surface chemistry |
| title | Supramolecular Assembly through Interactions between Molecular Dipoles and Alkali Metal Ions |
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