Electron Transfer in a Supramolecular Associate of a Fullerene Fragment

Herein, we investigate the association of a fullerene fragment, hemifullerene C30H12, with an electron‐donating bowl‐shaped tetrathiafulvalene derivative (truxTTF). UV/Vis titrations and DFT calculations support formation of the supramolecular complex, for which an association constant of log Ka=3.6...

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Veröffentlicht in:	Angewandte Chemie International Edition 2014-02, Vol.53 (8), p.2170-2175
Hauptverfasser:	Gallego, María, Calbo, Joaquín, Aragó, Juan, Krick Calderon, Rafael M., Liquido, Fernando H., Iwamoto, Takahiro, Greene, Allison K., Jackson, Edward A., Pérez, Emilio M., Ortí, Enrique, Guldi, Dirk M., Scott, Lawrence T., Martín, Nazario
Format:	Artikel
Sprache:	eng
Schlagworte:	Chloroform Constants density functional calculations Derivatives donor-acceptor systems Electron transfer Fragmentation Fullerenes Irradiation Mathematical analysis photoinduced electron transfer Room temperature supramolecular chemistry Titration
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